Recent Advances in Photochemical/Electrochemical Carboxylation of Olefins with CO_(2)  

作　　者：Qian Wang Yanwei Wang Min Liu Ganghui Chu Youai Qiu 

机构地区：[1]Xinjiang Laboratory of Native Medicinal and Edible Plant Resources Chemistry,College of Chemistry and Environmental Science,Kashi University,Kashi,Xinjiang 844000,China [2]state Key Laboratory and Institute of Elemento-Organic Chemistry,Frontiers Science Centerfor New Organic Matter,College of Chemistry Nankai University,94 Weijin Road,Tianjin 300071,China

出　　处：《Chinese Journal of Chemistry》2024年第18期2249-2266,共18页中国化学（英文版）

基　　金：Financial support from National Key R&D Program of China(2022YFA1503200);National Natural Science Foundation of China(Grant Nos.22371149,22188101,22301144);the Fundamental Research Funds for the Central Universities(No.63223015);Frontiers Science Center for New Organic Matter,Nankai University(Grant No.63181206)and Nankai University is gratefully acknowledged.

摘　　要：CO_(2) is an abundant,nontoxic,and renewable C1 feedstock in synthetic chemistry.Direct carboxylation of readily available olefins incorporating CO_(2) is regarded as a promising strategy to access high value-added carboxylic acids as well as CO_(2) fixation.However,due to the thermodynamic stability and kinetic inertness of CO_(2) and the difficulty in controlling the regioselectivity,the carboxylation of olefins with CO_(2) still remains challenging.Radical-type functionalization with olefins represented a powerful protocol and enabled the development of novel transformations in this realm.More recently,the advance of new technology,such as photoredox catalysis and the renaissance of electrochemistry in organic synthesis,offered access to unique chemical reactivities of radical precursors and provided new solutions to the functionalization of olefins.

关 键 词：CO_(2) CARBOXYLATION OLEFINS Photocatalysis ELECTROCATALYSIS RADICAL Reduction Difunctionalization 

分 类 号：O62[理学—有机化学]