EPOXIDES

作品数：94被引量：110H指数：4
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相关领域：理学更多>>
相关作者：樊娜高显区泽堂王莹张平更多>>
相关机构：湖南工程学院湖南大学华东理工大学中国药科大学更多>>
相关期刊：《Science China Chemistry》《High Power Laser Science and Engineering》《Chemical Research in Chinese Universities》《Chinese Journal of Polymer Science》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划国家教育部博士点基金俄罗斯基础研究基金更多>>
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Facile construction of heterogeneous dual-ionic poly(ionic liquid)s for efficient and mild conversion of CO_(2)into cyclic carbonates
《Journal of Environmental Sciences》2025年第3期177-187,共11页Guanqun Xie Jiaxiang Qiu Huadeng Li Hongbin Luo Shuo Li Yanbin Zeng Ke Zheng Xiaoxia Wang 
supported by the Applied Basic Research Foundation of Guangdong Province(No.2019A1515110551);the Science Foundation for Distinguished Scholars of Dongguan University of Technology(No.196100041051).
In the context of peaking carbon dioxide emissions and carbon neutrality,development of feasible methods for converting CO_(2)into high value-added chemicals stands out as a hot subject.In this study,P[D+COO^(−)][Br^(...
关键词：Dual-ionic poly(ionic liquid)s CO_(2)cycloaddition EPOXIDES Cyclic carbonates Heterogeneous catalysts 
A stable acyl cobalt-based catalyst with exceptionally elevated activity for the carbonylation of epoxides intoβ-lactones
《Chinese Journal of Catalysis》2025年第1期336-344,共9页Jianwei Jiang Vinothkumar Ganesan Inrack Choi Jeongcheol Shin Sungho Yoon Kiyoung Park 
Polyhydroxyalkanoate(PHA),a well-known biodegradable polymer,featuresβ-lactones as its monomers,which can be selectively synthesized through ring-expansion carbonylation of epoxides using well-defined[Lewis acid]^(+)...
关键词：Epoxide carbonylation β-Lactone Cobalttetracarbonyl Acyl cobalt carbonyl High-temperature catalytic activity 
Amine-functionalized metal-organic frameworks loaded with Ag nanoparticles for cycloaddition of CO_(2)to epoxides
《Frontiers of Chemical Science and Engineering》2024年第11期193-203,共11页Huiyu Fu Jiewen Wu Changhai Liang Xiao Chen 
National Key R&D Program of China(Grant No.2023YFB4103404);National Natural Science Foundation of China(Grant Nos.22272014 and 22161132005);Science and Technology Plan Project of Liaoning Province(Grant No.2023JH1/10400040);Fundamental Research Funds for the Central Universities(Grant No.DUT2021TD103).
With the advantages of low raw material cost and 100%atom utilization,the synthesis of high value-added chemical product cyclic carbonates by the cycloaddition of CO_(2)to epoxides has become one of the most prospecti...
关键词：CYCLOADDITION CO_(2)capture cyclic carbonates amine-functionalized UiO-66-NH_(2) Ag NPs 
Phosphine-Built-In Porous Organic Cage Supported Ultrafine Pd Nanoclusters Enable Highly Efficient and Regioselective Hydrogenation of Epoxides
《CCS Chemistry》2024年第10期2476-2488,共13页Xin Zhou Zhaozhan Wang Zhe-Ning Chen Yong Yang 
the National Natural Science Foundation of China(grant nos.22078350 and 22308368);the Shandong Province Key Research and Development Plan(grant no.2023CXG010607);the Natural Science Foundation of Shandong Province(grant nos.ZR2020KB016 and ZR2022QB026).
Selective hydrogenation of epoxides has been regarded as an atom-economical and straightforward method for the synthesis of alcohols.However,it remains a big challenge in the precise control of regioselectivity.To dat...
关键词：porous organic cage phosphine-built-in palladium nanoclusters regioselective hydrogenation EPOXIDES 
Dynamic Sulfur-Rich Polymers from Elemental Sulfur and Epoxides
《Chinese Journal of Polymer Science》2024年第10期1479-1487,I0010,共10页Ke-Xiang Chen Chen-Hui Cui Zhen Li Ting Xu Hao-Qing Teng Zhi-Yuan He Yin-Zhou Guo Xiao-Qing Ming Zhi-Shen Ge Yan-Feng Zhang Tie-Jun Wang 
financially supported by the State Key R&D Program of China (No. 2019YFA0706801);the National Natural Science Foundation of China (No. 52173079);the Fundamental Research Funds for the Central Universities (Nos. xtr052023001 and xzy022024024)。
Sulfur-containing dynamic polymers had attracted significant attention due to their unique chemical structures with high reversibility.Utilizating sulfur, an inexpensive industrial waste product, to synthesize dynamic...
关键词：Elemental sulfur Sulfur-containing polymer Dynamic covalent bond Dynamic polymer 
A Simple Synthesis of Tetraamino-[60]Fullerene Epoxides as Potential Antitumor Drug Candidates
《CCS Chemistry》2024年第10期2392-2399,共8页Yicheng Lu Jie Li Xiaolong Liu Dan He Libin Yang Wei Zhou Xie Wang Shanshan Chen Shiliang Chen Yating Liu Xin Wang Jiao Li Jiawei Huo Yang Liu Zehu Wang Meihan Liu Yijun Wang Yamin Li Fuwen Zhao Shumu Li Jinchao Wei Jianan Liu Wei Li Chunru Wang 
supported by the major research project of the National Natural Science Foundation of China(grant no.52272049);the National Key Research and Development Program of China(grant no.2022YFA1205900).
Amphiphilic aminated fullerenes have a broad margin of safety and significant antitumor effects.Herein,we develop a simple and versatile synthesis strategy for tetraamino-[60]fullerene epoxide(C_(60)(NR^(1)R^(2))_(4)O...
关键词：fullerene epoxides simple synthesis C_(60)Cl_(6) water-soluble aminated fullerene ANTITUMOR 
Highly active organocatalyst from a trivalent phosphazenium salt for ring-opening copolymerization of epoxides and cyclic anhydrides enhanced by hydrogen bonding interactions
《Science China Chemistry》2024年第9期3111-3120,共10页Chunhuan Jiang Junqi Wang Xiaoyu Liu Xiaoxia You Ronglin Zhong Chuanli Ren Zhibo Li 
supported by the National Key R&D Program of China(2021YFA1501600);National Natural Science Foundation of China(22031005)。
It is highly desirable to develop simple organocatalysts for the controlled ring-opening alternating copolymerization(ROAC)of epoxides and cyclic anhydrides,leading to high molecular weight polyesters.Hence,a phosphaz...
关键词：ring-opening copolymerization ORGANOCATALYST EPOXIDES cyclic anhydrides phosphazenium salt 
Visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO_(2)
《Chinese Chemical Letters》2024年第7期281-284,共4页Tian-Yu Gao Xiao-Yan Mo Shu-Rong Zhang Yuan-Xu Jiang Shu-Ping Luo Jian-Heng Ye Da-Gang Yu 
the National Natural Science Foundation of China (Nos. 22225106, 22301193);Fundamental Research Funds from Sichuan University (No. 2020SCUNL102);the Fundamental Research Funds for the Central Universities。
Herein, we report the first visible-light photoredox-catalyzed carboxylation of aryl epoxides with CO_(2)to synthesize hydroxy acid derivatives. A variety of valuable β-, γ-, δ-, ε–hydroxy acid derivatives are ob...
关键词：Carbon dioxide EPOXIDES Visible-light photoredox catalysis Hydroxy acid Sequential single electron transfer 
Random Terpolymer of Carbon Dioxide,Butadiene and Epoxides:Synthesis,Functionalization and Degradability
《Chinese Journal of Chemistry》2024年第14期1630-1636,共7页Zi Wang Wuyi Zheng Sicong Yue Kaihao Chen Jun Ling Xufeng Ni 
support by the Zhejiang Provincial Natural Science Foundation of China(No.LZ22B040001).
The utilization of carbon dioxide(CO_(2))as a C1 feedstock is consistently attractive,especially in the preparation of sustainable polymeric materials.In this contribution,a terpolymer of CO_(2),1,3-butadiene(BD)and e...
关键词：Ring-opening polymerization Copolymerization Carbon dioxide BUTADIENE Scandium triflate Fluorescence 
Cycloaddition Reactions of Epoxides and CO_(2)Catalyzed by Bifunctional Rare-Earth Metal Complexes Bearing Amino-Bridged Tris(phenolato)Ligands
《Chinese Journal of Chemistry》2024年第14期1571-1581,共11页Yongjie Chen Yanwei Wang Jun Nong Dan Yuan Yingming Yao 
the National Key R&D Program of China(2022YFF0709802);the National Natural Science Foundation of China(22271205);PAPD is gratefully acknowledged.
Eight zwitterionic rare earth metal complexes stabilized by amino-bridged tris(phenolato)ligands bearing quaternary ammonium side-arms were synthesized and characterized.These complexes were used as single-component c...
关键词：Bifunctional catalyst Carbon dioxide Cyclic carbonate Rare-earth metal Tris(phenolato)ligand Insertion Cycloaddition C1 building blocks 
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