Advances in the Synthesis of Carboxylic Acid by Photochemical Conversion of CO_(2)  

光化学转化二氧化碳合成羧酸化合物的研究进展

作　　者：Yuan Panfeng Zhu Canming Meng Qingyuan 袁盼锋;朱灿明;孟庆元(中国科学院化学研究所分子识别与功能实验室、北京分子科学国家研究中心,北京100190;中国科学院大学化学科学学院,北京100049)

机构地区：[1]Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory of Molecular Recognition and Function,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190 [2]School of Chemical Science,University of Chinese Academy of Sciences,Beijing 100049

出　　处：《有机化学》2024年第10期2997-3042,共46页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.22271293);中国科学院稳定支持基础研究领域青年团队计划(No.YSBR-050)资助项目.

摘　　要：The pursuit of cleanliness,energy efficiency,and resource preservation through photochemical reactions has led to the emergence of novel pathways and methodologies in synthetic chemistry,rendering it one of the most dynamic research domains within modern organic synthesis.Carbon dioxide(CO_(2)),owing to its non-toxic,cost-effective,abundant,and recyclable attributes,serves as an optimal C1 precursor in synthetic chemistry.Recent years have witnessed rapid advancements in the photochemical conversion of CO_(2) into carboxylic acid compounds,offering a gentle and highly efficient synthetic approach for their production.An overview of the research progress on the synthesis methodologies of carboxylic acid compounds through photochemical CO_(2) conversion is provided,while certain associated reaction mechanisms are also elucidated.光化学反应以洁净、节能、节约为目标,为合成化学提供了新途径和新方法,成为现代有机合成化学中非常活跃的研究领域之一.二氧化碳(CO_(2))由于其无毒、廉价易得、储量丰富且可循环再生等特点,是合成化学中理想的C1合成子.近年来,光催化促进的CO_(2)向羧酸化合物的转化得到了快速发展,为羧酸化合物的制备提供了一种温和并高效合成方法.综述了光催化转化CO_(2)合成羧酸化合物的合成方法研究进展,并对其部分反应机理做了相应的阐述.

关 键 词：carbon dioxide PHOTOCATALYSIS CARBOXYLATION 

分 类 号：O643.36[理学—物理化学] O644.1[理学—化学] O623.61