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AZIDES: 作品数：35被引量：45H指数：4; 导出分析报告; 相关领域：理学更多>>; 相关作者：焦宁夏旭东肖文精欧育湘李战雄更多>>; 相关机构：北京大学华中师范大学北京理工大学西北师范大学更多>>; 相关期刊：《Science China Chemistry》《Organic Chemistry Frontiers》《Chemical Research in Chinese Universities》《Journal of Beijing Institute of Technology》更多>>; 相关基金：国家自然科学基金中国博士后科学基金国家重点基础研究发展计划天津市自然科学基金更多>>

Gold-catalyzed intermolecular amination of allyl azides with ynamides:Efficient construction of 3-azabicyclo[3.1.0]scaffold: 《Chinese Chemical Letters》2025年第2期356-360,共5页Chong-Yang Shi Jian-Xing Gong Zhen Li Chao Shu Long-Wu Ye Qing Sun Bo Zhou Xin-Qi Zhu; financial support from the National Natural Science Foundation of China(Nos.22125108,22331004 and 22121001);Yunnan Normal University,Applied Basic Research Projects of Yunnan Province(No.202101AT070217);the Jiangxi Provincial Natural Science Foundation(No.20224BAB213013);the Jiangxi Provincial Department of Education in Science and Technology Program Project(No.GJJ210906)。; Gold-catalyzed amination reactions based on azides viaα-imino gold carbene intermediates have attracted extensive attention in the past decades because this methodology leads to the facile and efficient construction ...; 关键词：GOLD AZIDES Alkynes AMINATION HETEROCYCLES

Unlocking Biomolecular Activity through Pd-Catalyzed Azides Reduction: 《Chinese Journal of Chemistry》2024年第19期2305-2315,共11页Fang Fu Wei Xiong Xinyan Xu Yongjie Liu Ming Li Qianqian Qi Xingyu Liu Yuanyuan Zhang Tian Tian Xiang Zhou; the National Natural Science Foundation of China(Nos.22177089,21721005,92153303,22037004,22177088);the Fundamental Research Funds for the Central Universities(2042021kf0211);Translational Medicine and Interdisciplinary Research Joint Fund of Zhongnan Hospital of Wuhan University(Grant No.ZNJC202309).; Comprehensive Summary Pd-mediated bioorthogonal cleavage reactions have been extensively utilized in the activation of prodrug molecules,precise regulation of protein function,and cellular engineering.However,the avai...; 关键词：Decaging strategy PD-CATALYZED Azides reduction Biomolecular activation RNA regulation Biological activity Bioorganic chemistry PRODRUGS

Nickel/Photoredox Dual Catalytic Chan-Lam Coupling of Aryl Azides and Arylboric Acids: 《Chinese Journal of Chemistry》2024年第18期2228-2234,共7页Xia Ge Haojie Ji Hongjian Lu; financial support by the National National Natural Science Foundation of China(22271148,22071100).; Unsymmetrical diarylamines are crucial components in many pharmaceuticals and functional materials.In this study,we introduce an efficient Chan-Lam cross-coupling method that utilizes phenylboronic acids and aryl azid...; 关键词：AZIDES Chan-Lam reaction NICKEL Iridium Redox-neutral PHOTOCHEMISTRY

A General Electrochemical Synthesis of Sulfonimidoyl Fluorides,Azides,and Acetates: 《CCS Chemistry》2024年第8期2021-2030,共10页Yi-Min Jiang Yong-Ying Lin Lingyun Zhu Yi Yu Yuanming Li Yuqi Lin Ke-Yin Ye; the National Natural Science Foundation of China(grant no.22171046);the Hundred-Talent Project of Fujian(grant no.50021113)is gratefully acknowledged.; Sulfonimidoyl fluorides,the aza-bioisostere of sulfonyl fluorides,are emerging as a promising linkage agent in the sulfur(VI)fluoride exchange reaction(SuFEx).However,conventional synthetic approaches typically requir...; 关键词：ELECTROCHEMISTRY click chemistry sulfur(VI)fluoride exchange reaction sulfonimidoyl fluoride SULFINAMIDE

Synthesis of Unprotectedα-Tertiary Amines and 1,2-Amino Alcohols from Vinyl Azides by Light Induced Denitrogenative Alkylarylation/Dialkylation: 《CCS Chemistry》2024年第4期1060-1070,共11页Sifan Li Hai-Wu Du Paul W.Davies Wei Shu; This research was made possible as a result of a generous grant from NSFC(grant nos.21971101 and 22171127);Guangdong Basic and Applied Basic Research Foundation(grant no.2022A1515011806);Department of Education of Guangdong Province(grant nos.2022JGXM054 and 2021KTSCX106);Shenzhen Science and Technology Innovation Committee(grant no.JCYJ20220519201425001);Thousand Talents Program for Young Scholars,The Pearl River Talent Recruitment Program(grant no.2019QN01Y261);Guangdong Provincial Key Laboratory of Catalysis(grant no.2020B121201002).; Sterically congestedα-tertiary primary amines are ubiquitous substructures in pharmaceutical and agrochemical agents yet are challenging to access.Herein,straightforward photoredox-catalyzed access to structurally di...; 关键词：PHOTOCATALYSIS α-tertiary primary amines 1 2-amino alcohols vinyl azide electron donor-acceptor complex

Visible Light-Induced[3+2]Annulation Reaction of Alkenes with Vinyl Azides:Direct Synthesis of Functionalized Pyrroles被引量：1: 《Chinese Journal of Chemistry》2024年第2期151-156,共6页Ming Yang Xin-Yu Wang Jie Wang Yu-Long Zhao; financial support of this research by the National Natural Sciences Foundation of China(21871044 and 21472017).; A photocatalytic[3+2]annulation of alkenes with vinyl azides was developed under irradiation by visible light in the presence of organic dye photocatalysts.Broad substrate scope and high functional group tolerance wer...; 关键词：Photocatalysis Vinyl azides ALKENES PYRROLES ANNULATION Radical reactions

Asymmetric catalytic alkylation of vinyl azides with 3-bromo oxindoles: water-assisted chemo-and enantiocontrol: 《Science China Chemistry》2023年第3期799-807,共9页Ziwei Zhong Lichao Ning Yican Lu Jiuqi Tan Lili Lin Xiaoming Feng; supported by the National Natural Science Foundation of China(21871188,21921002);the Sichuan Science and Technology Program(2021YJ0561);the Sichuan University(2020SCUNL204)。; A highly chemo-and enantioselective alkylation of vinyl azides with 3-bromo-3-substituted oxindoles was achieved through a chiral N,N′-dioxide/Ni(OTf)2-mediated conjugate addition/water addition/elimination tandem pr...; 关键词：asymmetric catalysis water assistance tandem reaction vinyl azide ketone surrogate

Fluoro-substituted DPP-bisthiophene conjugated polymer with azides in the side chains as ambipolar semiconductor and photoresist: 《Science China Chemistry》2022年第9期1791-1797,共7页Wenlin Jiang Xiaobo Yu Cheng Li Xisha Zhang Guanxin Zhang Zitong Liu Deqing Zhang; supported by the National Key R&D Program of China(2018YFE0200700);the National Natural Science Foundation of China(22175081,21790363,61890943,22021002,22090021,22075293);the Key Research Program of the Chinese Academy of Sciences(XDPB13);the CAS-Croucher Funding Scheme for Joint Laboratories;Beijing National Laboratory for Molecular Sciences(BNLM202010);Guangdong Provincial Key Laboratory of Catalysis(20210701)。; Photoresists are essential for the fabrication of flexible electronics through all-photolithographic processes.Single component semiconducting photoresist exhibits both semiconducting and photo-patterning properties,a...; 关键词：conjugated polymer ambipolar semiconductor PHOTORESIST noncovalent conformation lock DIKETOPYRROLOPYRROLE

S-triggered Schmidt-type rearrangement of vinyl azides to access N-aryl-(trifluoromethylsulfinyl) acetamides: 《Organic Chemistry Frontiers》2022年第5期1241-1246,共6页Zhenhua Liu Tian Yu Longhua Li Wei Fu Xingxing Gan Huimin Chen Wen Gao Bo Tang; This work was supported by the National Natural Science Foundation of China(21976112 and 21775092);the National Key R&D Program of China(2019YFA0210100);the Major Science and Technology Innovation Project of Shandong Province(2021ZDSYS09);the Natural Science Foundation of Shandong Province of China(ZR2021MB031 and ZR2020JQ10);the Key Research and Development Program of Shandong Province(2018YFJH0502);the China Postdoctoral Science Foundation(2020M682204).; A novel S-induced Schmidt-type rearrangement of vinyl azides with CF_(3)SO_(2) Na is reported,which is mediated by triphosgene(BTC)under mild reaction conditions.A wide range of N-arylated 2-(trifluoro-methylsulfinyl)...; 关键词：conditions REARRANGEMENT AZIDE

Remote ether groups-directed regioselective and chemoselective cycloaddition of azides and alkynes: 《Chinese Chemical Letters》2021年第12期4019-4023,共5页Xuelun Duan Nan Zheng Ming Li Xinhao Sun Zhuye Lin Pan Qiu Wangze Song; supported by grants from the National Natural Science Foundation of China (No. 21978039);Special Funds of the Central Government Leading Local Government for the Technology Development (Nos. 2021JH6/10500146, 2021JH6/10500148);the Fundamental Research Funds for the Central Universities (Nos. DUT20YG120, DUT19LK60)。; Remote ether groups could be used as directing groups to prepare fully substituted 5-ether-1,2,3-triazoles with exclusive 1,5-regioselectivities and excellent chemoselectivities. Ether group could coordinate with irid...; 关键词：Remote ether Directing group Regioselectivity CHEMOSELECTIVITY Triazole

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