PD-CATALYZED

作品数:71被引量:47H指数:3
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相关领域:理学更多>>
相关作者:张勇健孙萌胡荣斌李霜谢应更多>>
相关机构:上海交通大学浙江大学华南理工大学西北大学更多>>
相关期刊:《Chemical Research in Chinese Universities》《Organic Chemistry Frontiers》《Science China Chemistry》《Chinese Journal of Polymer Science》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金高等学校学科创新引智计划更多>>
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Pd-Catalyzed Stereospecific Glycosyl Cross-Coupling of Reversed Anomeric Stannanes for Modular Synthesis of Nonclassical C‑Glycosides
《Precision Chemistry》2024年第11期587-599,共13页Guoqiang Cheng Bo Yang Yang Han Wei Lin Siyuan Tao Yong Nian Yingzi Li Maciej A.Walczak Feng Zhu 
sponsored by the National Key R&D Program of China(Grant No.2023YFA1508800);National Science Foundation(Grant No.22301178);Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(Grant No.21TQ1400210);Fundamental Research Funds for the Central Universities(Grant No.22X010201631);the Open Grant from the Pingyuan Laboratory(2023PY-OP-0102);Excellent Young Scientists Fund Program(Overseas),Natural Science Founda-tion of Shanghai(Grant No.21ZR1435600);Shanghai Sailing Program(Grant No 21YF1420600);start-up fundings from Shanghai Jiao Tong University(SJTU);Part of this study was supported by the National Science Foundation(Grant No.82204192 to Y.N.);National Key R&D Program of China(Grant No.2023YFC2308200 to Y.N.);Natural Science Foundation of Jiangsu Province(BK20220471 to Y.N.);Beatriu de Pinós programme from AGAUR(Grant No.2022 BP 00055 to Y.L);the China Postdoctoral Science Foundation(2022M722071 to B.Y.).
Nonclassical C-glycosides,distinguished by their unique glycosidic bond connection mode,represent a promising avenue for the development of carbohydrate-based drugs.However,the accessibility of nonclassical C-glycosid...
关键词:Glycosylation CROSS-COUPLING Nonclassical C-glycosides Reversed anomeric stannanes STEREOSPECIFICITY 
Unlocking Biomolecular Activity through Pd-Catalyzed Azides Reduction
《Chinese Journal of Chemistry》2024年第19期2305-2315,共11页Fang Fu Wei Xiong Xinyan Xu Yongjie Liu Ming Li Qianqian Qi Xingyu Liu Yuanyuan Zhang Tian Tian Xiang Zhou 
the National Natural Science Foundation of China(Nos.22177089,21721005,92153303,22037004,22177088);the Fundamental Research Funds for the Central Universities(2042021kf0211);Translational Medicine and Interdisciplinary Research Joint Fund of Zhongnan Hospital of Wuhan University(Grant No.ZNJC202309).
Comprehensive Summary Pd-mediated bioorthogonal cleavage reactions have been extensively utilized in the activation of prodrug molecules,precise regulation of protein function,and cellular engineering.However,the avai...
关键词:Decaging strategy PD-CATALYZED Azides reduction Biomolecular activation RNA regulation Biological activity Bioorganic chemistry PRODRUGS 
Pd-Catalyzed Dienylation of Propargylic Esters Enabling Highly Stereoselective Synthesis of Danishefsky-Type Trisubstituted Dienes
《Chinese Journal of Chemistry》2024年第17期1993-1998,共6页Chen Zhou Mengfu Dai Xiaoyu Yin Mingyue Zhang Weijin Gu Liang-An Chen 
funding from the National Natural Science Foundation of China(Nos.22071111 and 22371125);Jiangsu Specially Appointed Professor Plan,and Postgraduate Research&Practice Innovation Program of Jiangsu Province of China(No.KYCX23_1683).
The stereochemical synthesis of highly substituted Danishefsky-type dienes remains unsolved in organic chemistry.We describe a simple and efficient approach for the stereoselective synthesis of Danishefsky-type trisub...
关键词:Propargylic ester Dienylation DIENE STEREOSELECTIVITY CYCLOADDITION Palladium β-H elimination Regioselectivity 
Pd-catalyzed intermolecular Si–O formation via Si–C activation
《Science China Chemistry》2024年第8期2661-2669,共9页Shuang Liu Yu-Shu Chen Yichen Wu Peng Wang 
supported by the National Key R&D Program of China (2023YFF0723900);the National Natural Science Foundation of China (22371293, 22171277, 22101291, 21821002);the Program of Shanghai Academic/Technology Research Leader(23XD1424500);the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB0610000);Shanghai Institute of Organic Chemistry (SIOC);State Key Laboratory of Organometallic Chemistry for financial support。
The development of efficient Si–O bond formation reaction with 100% atom-economy, excellent functional group tolerance, and broad scope under mild conditions is highly desired due to the prevalence of silanol, silyl ...
关键词:Si–O formation Si–C activation palladium silacyclobutane SILANOL silyl ether 
Pd-Catalyzed Highly Regioselective Hydroesterification of Terminal Alkyl Olefins with Formates
《Chinese Journal of Chemistry》2024年第12期1381-1386,共6页Junhua Li Tianci Shen Yan Yang Yian Shi 
support from the National Natural Science Foundation of China(22271024,21632005)and Changzhou University.
Comprehensive Summary A Pd-catalyzed regioselective hydroesterification of alkyl terminal olefins with aryl formates is described.A wide variety of linear carboxylic esters bearing various functional groups can be obt...
关键词:ALKENES Regioselectivity CARBONYLATION HYDROESTERIFICATION FORMATES 
Pd-catalyzed asymmetric carbonyl alkynylation:Synthesis of axial chiral ynones
《Chinese Chemical Letters》2024年第6期293-297,共5页Long Jin Jian Han Dongmei Fang Min Wang Jian Liao 
supported financially by National Nature Science Foundation of China(No.22171258);the Youth Innovation Promotion Association CAS(No.2022375);the Biological Resources Programme,Chinese Academy of Sciences(No.KFJ-BRP-008);the Sichuan Science and Technology Program(No.2022ZYD0038)。
Ynones are important skeletons in bioactive molecules and valuable building blocks for organic synthesis,thus great efforts have been devoted to their preparation.While,introducing prochiral substrates to construct yn...
关键词:PD-CATALYZED Axial chiral ynones Cyclic diaryliodonium High-valent palladium catalyzed Asymmetric carbonyl alkynylation 
Recent Advances in Pd-Catalyzed Reactions Involving the “On-Water” Mechanism
《Chinese Journal of Chemistry》2024年第5期533-542,共10页Dong Wei Guo-Qiang Lin 
support from the National Natural Science Foundation of China(22101296);the State Key Laboratory of Systems Medicine for Cancer(SB23-09,KF2130-93).
As the chemical industry grapples with the need for more eco-friendly practices,the use of water as a reaction medium is gaining attraction in organic transformations.This mini-review delves into Pd-catalyzed reaction...
关键词:PD-CATALYZED “On-water” Green chemistry Aqueous reactions Mechanism Methodology and reactions Mizoroki-Heck reaction CROSS-COUPLING 
Pd-catalyzed diastereoselective 1,1-diarylation of 1,1-disubstituted alkenes enabling the modular synthesis of 1,1,2,2-tetraarylethanes
《Science China Chemistry》2023年第12期3539-3545,共7页Chengxi Zhang Yang Xi Jingping Qu Yifeng Chen 
supported by the National Natural Science Foundation of China (22171079);the Natural Science Foundation of Shanghai (21ZR1480400);the Shanghai Rising-Star Program (20QA1402300);the Shanghai Municipal Science and Technology Major Project (2018SHZDZX03);the Program of Introducing Talents of Discipline to Universities (B16017);the Fundamental Research Funds for the Central Universities。
The highly diastereoselective dicarbofunctionalization of substituted olefins still remains a daunting challenge in synthetic chemistry.Herein,we report a Pd-catalyzed diastereoselective 1,1-diarylation of 1,1-diaryle...
关键词:1 1 2 2-tetraarylethane PALLADIUM cross-coupling reaction ALKENE multicomponent reactions 
Palladium-Catalyzed[4+4]Cycloaddition of Homo-TMM All-Carbon 1,4-Dipole Precursors for Construction of Benzofuro[3,2-b]azocines and Furo[3,2-b]azocines被引量:2
《Chinese Journal of Chemistry》2023年第21期2825-2831,共7页Ying Chen Meng Zang Weije Wang Yang-zi Liu Xiaoyan Luo Wei-Ping Deng 
We are grateful for financial support from National Key Research and Development Program of China(2021YFA0804900);the NSFC(22171082,21971062);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(No.2022R01007);Shanghai Frontiers Science Center of Optogenetic Techniques for Cell Metabolism.
We developed a novel Pd-catalyzed[4+4]cycloaddition of(benzo)furan-derived azadienes with homo-TMM all-carbon 1,4-dipoles in situ generated fromα-allyl malonate derivatives,affording an array of benzofuro[3,2-b]azoci...
关键词:PD-CATALYZED [4+4]cycloaddition Homo-TMM 1 4-dipoles Methodology and reactions Medium-ring compounds Regioselectivity 
Pd-catalyzed cascade cyclization of allenylethylene carbonates and indandiones: Synthesis of tetracyclic dihydrocyclopentaindenofuranone derivatives
《Chinese Chemical Letters》2023年第10期131-134,共4页Yujie Dong Jun Liu Xing Gao Ting Pan Biming Mao Songcheng Yu Yongjun Wu Cheng Zhang Hongchao Guo 
supported by the Natural Science Foundation of China(Nos.21871293 and 22071264);。
A palladium-catalyzed cascade cyclization of allenylethylene carbonates with 1,3-indandiones was developed, providing biologically interesting tetracyclic dihydrocyclopentaindenofuranone derivatives having three conti...
关键词:PALLADIUM Allenylethylene carbonates Indandiones Cascade cyclization DECARBOXYLATION 
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