CARBONYLATION

作品数:127被引量:110H指数:4
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相关领域:理学更多>>
相关作者:李宇萍马隆龙张雪定明月王铁军更多>>
相关机构:中国科学院中国科学院大学江苏索普(集团)有限公司华东师范大学更多>>
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相关基金:国家自然科学基金中国博士后科学基金国家重点基础研究发展计划江苏省自然科学基金更多>>
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Impact of Various Silicon Sources on the Synthesis of Mordenite and Differences in the Carbonylation Reaction of Dimethyl Ether
《Chemical Research in Chinese Universities》2025年第1期59-65,共7页CHEN Long WANG Yunzheng LV Jiangang YANG Weimin 
This study introduces an innovative method for synthesizing mordenite(MOR)by employing a combination of water glass and fumed silica as the silica source.The zeolite produced through this method exhibits a smaller gra...
关键词:MORDENITE Silica source DME carbonylation 
A stable acyl cobalt-based catalyst with exceptionally elevated activity for the carbonylation of epoxides intoβ-lactones
《Chinese Journal of Catalysis》2025年第1期336-344,共9页Jianwei Jiang Vinothkumar Ganesan Inrack Choi Jeongcheol Shin Sungho Yoon Kiyoung Park 
Polyhydroxyalkanoate(PHA),a well-known biodegradable polymer,featuresβ-lactones as its monomers,which can be selectively synthesized through ring-expansion carbonylation of epoxides using well-defined[Lewis acid]^(+)...
关键词:Epoxide carbonylation β-Lactone Cobalttetracarbonyl Acyl cobalt carbonyl High-temperature catalytic activity 
Non-phosgene route:catalytic carbonylation of amines to form unsymmetrical ureas
《National Science Review》2025年第1期2-3,共2页Shunji Xie Ye Wang 
The production of unsymmetrical ureas,which are widely used in the pharmaceutical field[1],still relies heavily on the multi-steps reaction of two different amines with extremely toxic phosgene as the carbonyl source,...
关键词:AMINES steps CARBONYL 
Dimethoxymethane carbonylation and disproportionation over extra-large pore zeolite ZEO-1:Reaction network and mechanism
《Chinese Journal of Catalysis》2025年第1期230-245,共16页Shaolei Gao Peng Lu Liang Qi Yingli Wang Hua Li Mao Ye Valentin Valtchev Alexis T.Bell Zhongmin Liu 
国家自然科学基金(22472173);中国科学院青年创新促进会(2023193);山东能源研究院(SEIS202107);中国科学院青岛生物能源与过程研究所国际合作项目(202305).
Methyl methoxyacetate(MMAc)and methyl formate(MF)can be produced directly by heterogeneous zeolite-catalyzed carbonylation and disproportionation of dimethoxymethane(DMM),with near 100%selectivity for each process.Des...
关键词:Dimethoxymethane carbonylation Dimethoxymethane disproportionation ZEOLITE In-situ IR Kinetic Reaction mechanism 
Carbonylative transformation of aryl halides and strong bonds via cheap metal catalysts and sustainable technologies
《Green Synthesis and Catalysis》2024年第4期211-269,共59页Maolin Yang Yukun Liu Xin Qi Yanhua Zhao Xiao-Feng Wu 
financial support from the National Key R&D Program of China(No.2023YFA1507500);We also appreciate the general support provided by Prof.Armin Borner at Leibniz-Institute for Catalysis.
The development of catalytic carbonylation reactions has increased considerably.Although many reviews/chapters/books on carbonylation reactions have been published,summaries on cheap metal-catalyzed catalytic carbonyl...
关键词:CARBONYLATION Aryl halides(C(sp^(2))-X) Strong bonds C-Y(Y=O N H) Cheap metal Photochemical and electrochemical systems Green and sustainable chemistry 
Photon-induced regeneration of Pd catalyst for carbonylation of amines to ureas
《Chinese Journal of Catalysis》2024年第11期146-151,共6页Junbao Peng Jin Xie Zelong Li Can Li 
国家自然科学基金(22072061);国家重点研发计划(2021YFA15011).
Substituted ureas hold considerable significance in both natural and synthetic chemicals.Pd-based homogenous catalyst has been used for the urea synthesis,however the aggregation of Pd(0)species leads to the deactivat...
关键词:PHOTOCHEMISTRY CARBONYLATION Pd catalysis Pd regeneration UREA 
Constructing mesoporous CeO_(2)single-crystal particles in ionic liquids for enhancing the conversion of CO_(2)and alcohols to carbonates
《Chinese Journal of Catalysis》2024年第11期152-167,共16页Jielin Huang Jie Wang Haonan Duan Songsong Chen Junping Zhang Li Dong Xiangping Zhang 
中国科学院煤炭清洁燃烧与低碳利用先导科技专项(XDA29030202);国家自然科学基金(22178356);广东省重点领域研发计划(2020B0101370002).
Catalysts for CO_(2)value-added conversion have been extensively explored,but there is still a lack of systematic design for catalysts that achieve efficient CO_(2)conversion under mild conditions.Herein,we explored a...
关键词:Cerium dioxide Ionic liquid Single-crystal material Surface oxygen vacancy Carbonylation reaction 
Controlling Reactivity of Palladium Amides for Selective Carbonylation towards Urea and Oxamide Derivatives
《分子催化(中英文)》2024年第4期297-308,共12页WANG Jin-hui CAO Yan-wei HE Lin 
The National Key Research and Development Program of Ministry of Science and Technology(No.2022YFA1504602);Natural Science Foundation of Jiangsu Province(No.BK20211094);National Natural Science Foundation of China(No.22302214,21972152,U22B20137).
Carbonylation reactions,crucial for carbonyl group incorporation,struggle with the inherent complexity of achieving selective mono-or double-carbonylation on single substrates,often due to competing reaction pathways....
关键词:selectivity control palladium catalysis oxidative carbonylation AMINOCARBONYLATION green reagents 
Palladium-catalyzed carbonylation of activated alkyl halides via radical intermediates
《Industrial Chemistry & Materials》2024年第2期276-283,共8页Zhi-Peng Bao Xiao-Feng Wu 
financial support from DICP and K.C.Wong Education Foundation(GJTD-2020-08).
Palladium-catalyzed carbonylation is an efficient approach to prepare carbonyl-containing compounds with high atomic economy in synthetic organic chemistry.However,in comparison with aryl halides,carbonylation of alky...
关键词:Carbonyl group Palladium catalysis CARBONYLATION Activated alkyl halides Radical intermediates 
Pd-Catalyzed Highly Regioselective Hydroesterification of Terminal Alkyl Olefins with Formates
《Chinese Journal of Chemistry》2024年第12期1381-1386,共6页Junhua Li Tianci Shen Yan Yang Yian Shi 
support from the National Natural Science Foundation of China(22271024,21632005)and Changzhou University.
Comprehensive Summary A Pd-catalyzed regioselective hydroesterification of alkyl terminal olefins with aryl formates is described.A wide variety of linear carboxylic esters bearing various functional groups can be obt...
关键词:ALKENES Regioselectivity CARBONYLATION HYDROESTERIFICATION FORMATES 
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