This study introduces an innovative method for synthesizing mordenite(MOR)by employing a combination of water glass and fumed silica as the silica source.The zeolite produced through this method exhibits a smaller gra...
Polyhydroxyalkanoate(PHA),a well-known biodegradable polymer,featuresβ-lactones as its monomers,which can be selectively synthesized through ring-expansion carbonylation of epoxides using well-defined[Lewis acid]^(+)...
The production of unsymmetrical ureas,which are widely used in the pharmaceutical field[1],still relies heavily on the multi-steps reaction of two different amines with extremely toxic phosgene as the carbonyl source,...
Methyl methoxyacetate(MMAc)and methyl formate(MF)can be produced directly by heterogeneous zeolite-catalyzed carbonylation and disproportionation of dimethoxymethane(DMM),with near 100%selectivity for each process.Des...
financial support from the National Key R&D Program of China(No.2023YFA1507500);We also appreciate the general support provided by Prof.Armin Borner at Leibniz-Institute for Catalysis.
The development of catalytic carbonylation reactions has increased considerably.Although many reviews/chapters/books on carbonylation reactions have been published,summaries on cheap metal-catalyzed catalytic carbonyl...
Substituted ureas hold considerable significance in both natural and synthetic chemicals.Pd-based homogenous catalyst has been used for the urea synthesis,however the aggregation of Pd(0)species leads to the deactivat...
Catalysts for CO_(2)value-added conversion have been extensively explored,but there is still a lack of systematic design for catalysts that achieve efficient CO_(2)conversion under mild conditions.Herein,we explored a...
The National Key Research and Development Program of Ministry of Science and Technology(No.2022YFA1504602);Natural Science Foundation of Jiangsu Province(No.BK20211094);National Natural Science Foundation of China(No.22302214,21972152,U22B20137).
Carbonylation reactions,crucial for carbonyl group incorporation,struggle with the inherent complexity of achieving selective mono-or double-carbonylation on single substrates,often due to competing reaction pathways....
financial support from DICP and K.C.Wong Education Foundation(GJTD-2020-08).
Palladium-catalyzed carbonylation is an efficient approach to prepare carbonyl-containing compounds with high atomic economy in synthetic organic chemistry.However,in comparison with aryl halides,carbonylation of alky...
support from the National Natural Science Foundation of China(22271024,21632005)and Changzhou University.
Comprehensive Summary A Pd-catalyzed regioselective hydroesterification of alkyl terminal olefins with aryl formates is described.A wide variety of linear carboxylic esters bearing various functional groups can be obt...