Pd-Catalyzed Highly Regioselective Hydroesterification of Terminal Alkyl Olefins with Formates  

作　　者：Junhua Li Tianci Shen Yan Yang Yian Shi 

机构地区：[1]Jiangsu Key Laboratory of Advanced Catalytic Materials&Technology,Schoolof Petrochemical Engineering,Institute of Natural and Synthetic Organic Chemistry,Changzhou University,Changzhou,Jiangsu 213164,China

出　　处：《Chinese Journal of Chemistry》2024年第12期1381-1386,共6页中国化学（英文版）

基　　金：support from the National Natural Science Foundation of China(22271024,21632005)and Changzhou University.

摘　　要：Comprehensive Summary A Pd-catalyzed regioselective hydroesterification of alkyl terminal olefins with aryl formates is described.A wide variety of linear carboxylic esters bearing various functional groups can be obtained in good yields with high regioselectivities under mild reaction conditions by using 1,2-DTBPMB or(p-F-Ph)3P as ligand.The reaction process is operationally simple and requires no handling of toxic CO or strong acid.The resulting aryl esters can be readily converted to other carboxylic acid derivatives.

关 键 词：ALKENES Regioselectivity CARBONYLATION HYDROESTERIFICATION FORMATES 

分 类 号：O62[理学—有机化学]