financially supported by an internal fund from Tsinghua University。
The burgeoning ethylene production in the Asia-Pacific region has led to a substantial oversupply of butadiene as a byproduct,and it is highly important to develop new butadiene-based materials.Butadiene-maleic anhydr...
the National Natural Science Foundation of China(22171201 and 22371185);the Fundamental Research Funds for the Central Universities(23x010301599,24x010301678);the Program of Shanghai Academic/Technology Research Leader(23XD1421900).
An efficient transannular cyano migration is reported for gem-dicyano-1,6-diene,which is triggered by the addition of external arylsulfonyl radicals.The overall transformation proceeds through a sequence of intramolec...
Adenosine triphosphate(ATP)-citrate lyase(ACLY)converts cytosolic citrate from the tricarboxylic acid cycle(TCA cycle)into acetyl coenzyme A(acetyl-CoA),which is a building block for cholesterol and fatty acid synthes...
funding from the National Natural Science Foundation of China(Nos.22071111 and 22371125);Jiangsu Specially Appointed Professor Plan,and Postgraduate Research&Practice Innovation Program of Jiangsu Province of China(No.KYCX23_1683).
The stereochemical synthesis of highly substituted Danishefsky-type dienes remains unsolved in organic chemistry.We describe a simple and efficient approach for the stereoselective synthesis of Danishefsky-type trisub...
supported by the National Key Research and Development Program of China(grant no.2021YFF0701700);the National Natural Science Foundation of China(grant nos.21925105,92156001,and 22101141);the Natural Science Foundation of Tianjin(grant no.18JCJQJC47000);the Haihe Laboratory of Sustainable Chemical Transformations,and the Fundamental Research Funds for the Central Universities.
A rhodium/diene catalyzed asymmetric allylic trifluoromethoxylation reaction is reported,which afforded chiral trifluoromethoxylated allylic compounds in 52%–97%yields with up to 97%enantiomeric excess.These are the ...
Supported by National Key Research and Development Program of China(2022 YFB 3704700(2022 YFB 3704702));Major Scientific and Technological Innovation Project of Shandong Province(2021 CXGC 010901);Taishan Scholar Program。
Heterogeneous TiCl4/MgCl_(2) type Ziegler-Natta(Z-N)catalysts with unique advantages like low cost,high activity,high stereoregularity and pretty particle morphology,contribute to more than 130 Mt polyolefin large-sca...
National Natural Science Foundation of China,Grant/Award Numbers:U20A20308,52277024;Heilongjiang Provincial Natural Science Foundation of China,Grant/Award Number:LH2020E093。
Rubber-based composites based on ethylene propylene diene monomer(EPDM)with excellent non-linear electrical conductivity are preferred to serve as reinforced insu-lation in cable accessories,which can self-adaptively ...
supported by the National Natural Science Foundation of China (22271203);the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry(KF2021005);the Collaborative Innovation Center of Suzhou Nano Science and Technology;the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)。
In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switchin...
the National Natural Science Foundation of China(NSFC,No.22071262);Science and Technology Commission of Shanghai Municipality(No.22ZR1475200);Shanghai Rising-Star program(No.20QA1411300);CAS Key Laboratory of Synthetic Chemistry of Natural Substances,and Shanghai Institute of Organic Chemistry for financial support.
Because of the widespread applications of optically active alkyl fluorides in medicinal and agro chem-icals,enantioselective and even stereodivergent construction of alkyl fluorides remains highly desirable but underd...