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ENANTIOSELECTIVE: 作品数：269被引量：197H指数：5; 导出分析报告; 相关领域：理学更多>>; 相关作者：夏飞刘秀艳皮超张俊良曾苏更多>>; 相关机构：华东师范大学郑州大学南开大学中国科学技术大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>

Enantioselective copper-catalyzed dearomative borylative cyclization of indoles and mechanistic insights: 《Science China Chemistry》2025年第2期670-678,共9页Yanfei Li Xuetao Li Zheng Zhang Yiliang Zhang Xiuping Yuan Jianjun Yin Simin Wang Wei Guan Qian Zhang Tao Xiong; supported by the Natural Science Foundation of Jilin Province(20210101134JC);the National Natural Science Foundation of China(22171042,21831002,22193012);the Fundamental Research Funds for the Central Universities.; Alicyclic nitrogen heterocycles,such as enantioenriched polycyclic fused[1,2-a]indoline derivatives,are widespread in natural products,agrochemicals and pharmaceutical agents.Existing methods predominantly rely on the...; 关键词：copper catalysis DEAROMATIZATION borylative cyclization INDOLES DFT calculations

Enantioselective biosynthesis of vicinal diamines enabled by synergistic photo/biocatalysis consisting of an ene-reductase and a green-light-excited organic dye: 《Chinese Journal of Catalysis》2025年第1期223-229,共7页Fengming Shi Bin Chen Jinhai Yu Ruiqi Zhu Yu Zheng Xiaoqiang Huang; 国家自然科学基金(22277053);国家重点研发计划(2022YFA0913000);江苏省自然科学基金项目(BK20220760);南京大学卓越计划(ZYJH004)。; Vicinal diamines are key motifs widely-found in many pharmaceuticals and biologically active molecules.An appealing approach for synthesizing these molecules is the amination of enamines,but few examples have been exp...; 关键词：Photobiocatalysis Vicinal diamines Asymmetric synthesis HYDROAMINATION Green light excitation

Reduction of Tertiary Carbon Radicals via Asymmetric Hydrogen Atom Transfer(AHAT): 《Chinese Journal of Chemistry》2024年第24期3414-3428,共15页Xue Han Chuan He; the National Natural Science Foundation of China(22122102,22271134);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);Guangdong Peari River Talent Program(2019QN01Y628);ShenzhenScience and Technology Innovation Committee(RCJC20221008092723013,JCYJ20230807093104009).; In the past two decades,the development of asymmetric radical reactions has achieved tremendous progress,which has emerged as a powerful tool for the synthesis of chiral molecules in synthetic chemistry.Among the dive...; 关键词：AHAT Radical reactions Asymmetric synthesis Enantioselective radical reactions Hydrogen atom transfer CHIRALITY REDUCTION Synthetic methods

Enantioselective Borylative Functionalization of Internal Alkenes:A Platform for Constructing Vicinal Stereocenters: 《Chinese Journal of Chemistry》2024年第24期3588-3604,共17页Yu-Shen Zhu Jia-Xin Li Hao-Tian Zhao Bo Su; National Natural Science Foundation of China(22271161,22188101);the Tianjin Science Fund for Distinguished Young Scholars(23JCJQJC00180);the Fundamental Research Funds for the Central Universities(63233165,63243134);Nankai University,for financial support.; Vicinal stereogenic centers are ubiquitous structural scaffolds in both natural products and synthetic compounds,yet their enantioselective construction remains a significant challenge in organic synthesis.Organoboron...; 关键词：Borylative functionalization ORGANOBORON Vicinal stereogenic centers Transition metal catalysis Asymmetric synthesis

Catalytic Enantioselective Functionalization of Maleimides:An Update: 《Chinese Journal of Chemistry》2024年第24期3605-3622,共18页Muriel Amatore Damien Bonne Thierry Constantieux Jean Rodriguez; Maleimide derivatives are well-established reactive intermediates also found in natural products,synthetic pharmaceuticals and functional polymers.Their specific reactivity found widespread applications in the field o...; 关键词：MALEIMIDES Enantioselective catalysis ADDITIONS CYCLOADDITIONS HETEROCYCLES Domino reactions

Palladium/Xu-Phos-catalyzed enantioselective arylalkoxylation reaction ofγ-hydroxyalkenes at room temperature: 《Chinese Chemical Letters》2024年第11期355-360,共6页Shuai Zhu Mingjie Chen Haichao Shen Hanming Ding Wenbo Li Junliang Zhang; funding support of the National Natural Science Foundation of China(NSFC,Nos.22071060 and 22031004);the National Key R&D Program of China(No.2021YFF0701600);Shanghai Municipal Education Commission(No.20212308)。; Metal-catalyzed alkene arylalkoxylation is a powerful complexity-building strategy for the synthesis of oxygen heterocycles from simpleγ-unsaturated alcohols,but only a few examples of catalytic enantioselective meth...; 关键词：Palladium-catalysis Xu-Phos ENANTIOSELECTIVE Arylalkoxylation γ-Hydroxyalkenes

Asymmetric macrocyclization enabled by Rh(Ⅲ)-catalyzed C-H activation:Enantioenriched macrocyclic inhibitor of Zika virus infection: 《Chinese Chemical Letters》2024年第11期378-383,共6页Chao Chen Wenwen Yu Guangen Huang Xuelian Ren Xiangli Chen Yixin Li Shenggui Liang Mengmeng Xu Mingyue Zheng Yaxi Yang He Huang Wei Tang Bing Zhou; supported by National Natural Science Foundation of China(No.81973166);Science and Technology Commission of Shanghai Municipality(No.22XD1424600);Natural Science Foundation of Shanghai Municipality(No.22ZR1474100);Taishan Scholar Foundation of Shandong Province(No.tsqn202306322);National Key R&D Program of China(No.2021YFC2300700);Shandong Laboratory Program(No.SYS202205);Shandong Provincial Natural Science Foundation(Nos.ZR2023LSW003 and ZR2023JQ028)。; The development of enantioselective C-H macrocyclizations to efficiently access structurally diversified macrocycles is highly desirable,but remain a big challenge.Herein,we reported the first rhodium(Ⅲ)-catalyzed as...; 关键词：C-H activation Carboamidation Enantioselective macrocyclization Anti-Zika virus activity

Enantioselective iridium-catalyzed allylic substitution with a Reformatsky reagent: direct construction of β-stereogenic homoallylic esters: 《Science China Chemistry》2024年第11期3791-3797,共7页Debasis Pal Kirana DVeeranna Yuk Fai Wong PAndrew Evans; the National Sciences and Engineering Research Council (NSERC) for a Discovery Grant;supporting a Tier 1 Canada Research Chair (P.A.E);the Huxiang High-Level Talent Gathering Project from the Science and Technology Department of Hunan Province (Grant No. 2020RC5001)。; The Reformatsky reagent derived from ethyl bromoacetate circumvents the challenge associated with the direct regio-and enantioselective iridium-catalyzed allylic alkylation with an unstabilized aliphatic ester enolate...; 关键词：allylic substitution asymmetric catalysis mechanistic studies natural product synthesis Reformatsky reagent

Construction of Planar Chiral Ferrocenes by Cobalt-Catalyzed Enantioselective C–H Acyloxylation Enabled by Dual Ligands: 《CCS Chemistry》2024年第11期2783-2793,共11页Fan-Rui Huang Peng Zhang Qi-Jun Yao Bing-Feng Shi; supported by the National Key R&D Program of China(grant nos.2021YFF0701603 and 2022YFA1504302);the National Natural Science Foundation of China(grant nos.21925109,U22A20388,and 92256302);the Fundamental Research Funds for the Central Universities(grant nos.226-2023-00115 and 226-2022-00224);the College of Material Chemistry and Chemical Engineering,Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,Hangzhou Normal University(grant no.KFJJ2023003).; Oxy-substituted planar chiral ferrocenes are of great importance in asymmetric synthesis and pharmaceuticals.However,enantioselective C–H activation of ferrocenes that form C–O bonds remains a huge challenge and has...; 关键词：C–H acyloxylation COBALT dehydrogenative coupling ENANTIOSELECTIVITY FERROCENES

Palladium/Xu-Phos Catalyzed Enantioselective Intramolecular Heck Reaction of Unactivated Alkenes: 《Chinese Journal of Chemistry》2024年第20期2466-2470,共5页Lujia Zhou Longling Ma Bing Xu Zhan-Ming Zhang Junliang Zhang; support of the National Key R&D Program of China(No.2021YFF0701600),NSFC(No.22031004);the Shanghai Municipal Education Commission(No.20212308);China Postdoctoral Science Foundation(No.2022M713667)and STCSM(No.23ZR1445600).; A highly enantioselective palladium-catalyzed intramolecular Heck reaction of unactivated alkenes is developed,which provides a powerful route to access a broad range of chiral 3,3-disubstituted-2,3-dihydrobenzofurans...; 关键词：PALLADIUM HECK 2 3-Dihydrobenzofuran Asymmetric catalysis Quaternary stereocenter ENANTIOSELECTIVE P ligands ALKENES

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