ORGANOBORON

作品数：28被引量：22H指数：2
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相关作者：于杨王浩许斌王楠更多>>
相关机构：上海大学北京理工大学更多>>
相关期刊：《Smart Molecules》《Organic Chemistry Frontiers》《Journal of Cancer Therapy》《Science China Chemistry》更多>>
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Recent Advances of Boron-Containing Chiral Luminescent Materials
《Chinese Journal of Chemistry》2025年第2期219-238,共20页Jiaqi Di Shuran Han Pangkuan Chen 
supported by the National Natural Science Foundation of China(Nos.22271013 and 21772012);the Beijing Natural Science Foundation(No.2232024).
As a class of organic dyes,boron-containing compounds play an important role in organic luminescent materials.They have attracted considerable attention due to their unique photophysical properties.Chiral luminescent ...
关键词：Organoboron Chirality Circularly dichroism Circularly polarized luminescence Luminescent materials 
Enantioselective Borylative Functionalization of Internal Alkenes:A Platform for Constructing Vicinal Stereocenters
《Chinese Journal of Chemistry》2024年第24期3588-3604,共17页Yu-Shen Zhu Jia-Xin Li Hao-Tian Zhao Bo Su 
National Natural Science Foundation of China(22271161,22188101);the Tianjin Science Fund for Distinguished Young Scholars(23JCJQJC00180);the Fundamental Research Funds for the Central Universities(63233165,63243134);Nankai University,for financial support.
Vicinal stereogenic centers are ubiquitous structural scaffolds in both natural products and synthetic compounds,yet their enantioselective construction remains a significant challenge in organic synthesis.Organoboron...
关键词：Borylative functionalization ORGANOBORON Vicinal stereogenic centers Transition metal catalysis Asymmetric synthesis 
Photoresponsive tetracoordinate arylboron smart molecules: Strategies for molecular design and photoresponse mechanisms
《Smart Molecules》2024年第4期105-123,共19页Jinjin Wang Mengzhen Li Haoyu Gao Lixia Xie Xin Zheng Guoxing Liu Tianjing Wu Lu Lin Lijie Liu 
supported by the Topnotch Talents Program of Henan Agricultural University(30501032,30500418,30501049);the National Natural Science Foundation of China(22305070,U20041101);the Natural Science Foundation of Henan Province(232300420132);the Scientific and Technological Project of the Henan Province(222102240043);the Distinguished Young Scholar Fund Project of Hunan Province Natural Science Foundation(2023JЛ10041)。
Photoresponsive smart materials,which exhibit swift or instantaneous responses to external light stimuli,are pivotal for advancing the development of novel smart devices.Among these materials,photoresponsive tetracoor...
关键词：organoboron photochemistry organoboron photochromism organoboron photoisomerization organoboron photoresponsive materials 
Borane-Catalyzed Asymmetric Reduction of 2-Alkylpyridines
《Chinese Journal of Chemistry》2024年第23期3088-3092,共5页Heng Luo Zhao-Ying Yang Ming Zhang Xiao-Chen Wang 
the National Natural Science Foundation of China(Nos.22371141,22221002);National Key R&D Program of China(No.2021YFA1500200);Natural Science Foundation of Tianjin(No.20JCJQJC00030);Haihe Laboratory of Sustainable Chemical Transformations(No.ZYT202101);Frontiers Science Center for New Organic Matter at Nankai University(No.63181206);Tencent Foundation for financial support.
Herein,a method for the enantioselective reduction of unprotected 2-alkylpyridines is reported for the first time.By using pinacolborane and an amide as reducing agents,a large number of 2-alkylpiperidines were synthe...
关键词：ORGANOBORON Asymmetric Catalysis PYRIDINE PIPERIDINE Heterocycles Homogeneous catalysis Reduction CHIRALITY 
Boron-Stereogenic Compounds:Synthetic Developments and Opportunities
《Chinese Journal of Chemistry》2024年第19期2401-2411,共11页Yonghong Guo Bing Zu Cadmus Du Chen Chuan He 
the National Natural Science Foundation of China(22122102,22271134);Guangdong Provincial Key Laboratory of Catalysis(2020B121201002);Guangdong Pearl River Talent Program(2019QN01Y628);Shenzhen Scienceand TechnologyyInnovationCommittee(RCJC20221008092723013,JCYJ20230807093104009);Hebei ProvinceInnovationCapability Enhancement Plan Project(22567632H).
Comprehensive Summary The 21st century has witnessed a continuous evolution in the development of boron-stereogenic chemistry.Since the 1990s,various innovations for the synthesis of tetracoordinate boron-stereogenic ...
关键词：Chiral organoboron Boron-stereogenic compounds Chiral resolution Asymmetric synthesis Asymmetric catalysis Chirality Heterocycles CHELATES 
An n-type organoboron polymer for red-light-selective organic photodetectors
《Science Bulletin》2024年第16期2501-2504,共4页Xu Cao Hongkun Tian Lu Zhang Jun Liu Lixiang Wang 
supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0520103);the National Natural Science Foundation of China(22135007 and 52073281)。
Color-selective light detection is required for high-resolution imaging,optical communication,biomedical applications,and so on[1,2].Typical photodetectors using broad-band absorption materials as the active layers ex...
关键词：light SELECTIVE BORON 
Aggregation-Induced Emission(AIE)Active Fluoroboronated Pyridylhydrazinyl Aldehyde Hydrozone Dyes:Synthesis,Crystal Structure and Optical Properties
《有机化学》2024年第8期2545-2553,共9页Gong Qingbao LüXiang Yu Changjiang Li Wanwan Zhao Quansheng Jiao Lijuan Hao Erhong 
国家自然科学基金(No.22271002);安徽省自然科学基金(Nos.2008085QB67,2308085J14);安徽省高等学校科学研究项目(Nos.2023AH050149,KJ2021A0126);安徽省教育厅高校优秀科研创新团队(No.2022AH010073)资助项目.
A new family of fluoroboronated pyridylhydrazinyl aldehyde hydrozone fluorophores named BOPAHs were developed via a simple one-pot two-step reaction from chloro-2-hydrazinylpyridine and aromatic aldehyde derivatives.T...
关键词：aggregation-induced emission organoboron dyes organic synthesis optical properties 
Theoretical investigation of photoelectric properties of the four-coordinate organoboron compounds based on diketopyrrolopyrrole derivativ
《分子科学学报》2024年第2期153-159,共7页XING Lihua JIN Ruifa 
the National Natural Science Foundation of China(21563002);the Natural Science Foundation of Inner Mongolia Autonomous Region(2021LHMS02001);the Research Program of Sciences at Universities of Inner Mongolia Autonomous Region(NJZY21175)
In order to obtain high efficiency of organic light-emitting diodes and organic solar cells,a series of DPP-based four-coordinate organoboron compounds have been designed for photoelectric functional materials.The eff...
关键词：DIKETOPYRROLOPYRROLE four-coordinate organoboron compound density functional theory optical property organic solar cell organic light-emitting diodes 
Ni-catalyzed highly regio- and stereo-selective diborylative cyclization of 1,6-enynes with diboron reagent
《Science China Chemistry》2024年第3期981-989,共9页Qitao Guan Zhen Shen Yiqiang Tian Genping Huang Chun Zhang 
supported by Tianjin University(B22021-010);the State Key Laboratory of Elemento-Organic Chemistry;the National Natural Science Foundation of China(22371203,22073066,21503143,21975179)。
The Ni-catalyzed highly selective diborylative cyclization of 1,6-enynes with diboron reagent has been developed. When pinB-Bdan was used, multiple types of boron-containing functional groups could be installed into o...
关键词：NICKEL-CATALYZED ORGANOBORON CYCLIZATION regioselectivity ENANTIOSELECTIVITY 
Sigmatropic rearrangements of B(MIDA)-propargylic alcohols towards the diverse synthesis of α-functionalized organoborons
《Science China Chemistry》2024年第2期568-575,共8页Jiasheng Qian Li-Cai Liu Zhi-Hao Chen Yuan Liu Yin Li Qingjiang Li Honggen Wang 
supported by the National Natural Science Foundation of China (22022114,21971261);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01Y093);Guangdong Basic Research Center of Excellence for Functional Molecular Engineering。
α-Functionalized organoborons are useful building blocks and key structural elements in functional molecules.Their previous synthesis relied on the famous Matteson reaction or the late-stage borylative modification o...
关键词：ORGANOBORON diverse synthesis sigmatropic rearrangement HETEROARENE AMIDE 
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