National Natural Science Foundation of China(Project No.:52320105003,Project No.:52303019);the CAS-ANSO Co-funding Research Project(Project No.:CAS-ANSO-CF-2024);the National Key R&D Program of China(Project No.:2023YFC3707201);the Fundamental Research Funds for the Central Universities(Project No.:E3ET1803);China Postdoctoral Science Foundation(Project No:2024T170904)。
The valorization of nitrous oxide(N_(2)O)as an oxygen atom donor presents an attractive opportunity for green chemistry applications,leveraging both its industrial abundance and thermodynamically favorable oxidation p...
financial support from the National Natural Science Foundation of China(NSFC,No.21877067);Tsinghua-Peking Centre for Life Science。
Herein,we describe a nickel-catalyzed reductive decarboxylative difluoromethylation reaction of alkenes using inexpensive and easy-to-handle difluoroacetic anhydride(DFAA)/pyridine N-oxide reagent system.A variety of ...
supported by Guangdong Basic and Applied Basic Research Foundation(2024A1515011689).
Chiral 1,3-substituted fragments are ubiquitous in pharmaceutical molecules and natural products,prompting the development of numerous methods to access these structures.Nonetheless,devising synthetic routes for compl...
financial support from the National Natural Science Foundation of China(No.22001147);Taishan Scholars Project of Shandong Province(No.tsqn202103027);Distinguished Young Scholars of Shandong Province(Overseas)(No.2022HWYQ-001);Qilu Youth Scholar Funding of Shandong University。
Aromatic aldehydes are the most fundamentally important compounds used in organic synthesis.The development of new synthetic methods for introduction of a formyl group into an organic scaffold is highly desirable.In t...
sponsored by the National Key R&D Program of China(Grant No.2023YFA1508800);National Natural Science Foundation of China(Grant No.22301178);Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(Grant No.21TQ1400210);Fundamental Research Funds for the Central Universities(Grant No.22x010201631);the Open Grant from the Pingyuan Laboratory(2023PY-OP-0102);Excellent Young Scientists Fund Program(Overseas);Natural Science Foundation of Shanghai(Grant No.21ZR1435600).
A highly stereoselective nickel-catalyzed cross-electrophile coupling of readily accessible,novel,stable oxygen-based glycosyl radical precursors,specifically 1,2-glycosyl orthoesters,is developed.This approach offers...
financial support from National Natural Science Foundation of China(22071187,22271226);Natural Science Foundation of Hubei Province(2021CFA069);National Youth Talent Support Program。
Transition metal-catalyzed asymmetric hydrogenation is an efficient and direct synthetic method to access chiral compounds,which features simplicity,easy working-up process,and high atomic economy.It typically relies ...
supported by the National Natural Science Foundation of China(22361003,82260676);Talent Project of Jiangxi Province(jxsq2019101065);the Jiangxi Provincial Natural Science Foundation(20224BAB216005,20232BAB216131);the Science and Technology Projects of Ganzhou(202101094462,2023PNS26854);The Start-up Fund of Gannan Medical University.
Herein,an unprecedented nickel-catalyzed regioselective hydroalkynylation of unsymmetrical internal alkynes was realized with steric hindered resistance selectivity via the cyano-directing group strategy.Significantly...
supported by the National Natural Science Foundation of China(22322108);Natural Science Foundation of Jiangsu Province(BK20231521 and BK20221355);Jiangsu Specially Appointed Professors Plan(SR10900122),and start-up funds from Soochow University.
Given the importance of alkenylsilanes in organosilicon chemistry and material science, direct transition-metal-catalyzed selective hydrosilylation of alkynes with hydrosilanes has emerged as apowerful platform for ac...
the National Natural Science Foundation of China(22278265,U22B20137 and 22203069);the Zhejiang Provincial Natural Science Foundation of China(LR24B020002);the start-up funding from Hangzhou Normal University(4095C50222204165 and 4095C50223204074);the Interdisciplinary Research Project of Hangzhou Normal University(2024JCXK04)for financial support of this research。
The transition-metal-catalyzed migratory functionalization has emerged as a robust protocol for the building of C–C bonds remote from the“initiation”position.However,a similar strategy for the construction of quate...
supported by the National Natural Science Foundation of China(21971074,22001076);the Natural Science Foundation of Guangdong Province(2022A1515010660,2021A1515220024);the Natural Science Foundation of Guangzhou(202102020982)。
Herein,a nickel-catalyzed arylcyanation of unactivated alkenes via cyano group translocation with aryl boronic acids has been developed.These transformations provided a robust approach to constructing structurally div...