NICKEL-CATALYZED

作品数:71被引量:62H指数:5
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相关领域:理学更多>>
相关作者:曾程初谢湖均龚和贵更多>>
相关机构:浙江工商大学广西师范大学广州医科大学西南大学更多>>
相关期刊:《Journal of Electronic Research and Application》《Science China Chemistry》《Science Bulletin》《Engineering》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划湖北省自然科学基金福建省自然科学基金更多>>
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Electrochemically Driven Nickel-Catalyzed Phenol Synthesis via Sustainable Oxygen Atom Transfer from Nitrous Oxide
《Journal of Electronic Research and Application》2025年第2期18-22,共5页Qiyu Zhang Wenbin Xie Yasser M.A.Mohamed Hossam A.El Nazer Ahmed A.Elnazer Yinghui Han 
National Natural Science Foundation of China(Project No.:52320105003,Project No.:52303019);the CAS-ANSO Co-funding Research Project(Project No.:CAS-ANSO-CF-2024);the National Key R&D Program of China(Project No.:2023YFC3707201);the Fundamental Research Funds for the Central Universities(Project No.:E3ET1803);China Postdoctoral Science Foundation(Project No:2024T170904)。
The valorization of nitrous oxide(N_(2)O)as an oxygen atom donor presents an attractive opportunity for green chemistry applications,leveraging both its industrial abundance and thermodynamically favorable oxidation p...
关键词:Nitrous oxide Electrochemical synthesis Aryl iodides Revalorization Nickel-catalysis 
Nickel-catalyzed decarboxylative difluoromethylation and alkylation of alkenes
《Chinese Chemical Letters》2025年第3期253-258,共6页Zhenkang Ai Hui Chen Xuebin Liao 
financial support from the National Natural Science Foundation of China(NSFC,No.21877067);Tsinghua-Peking Centre for Life Science。
Herein,we describe a nickel-catalyzed reductive decarboxylative difluoromethylation reaction of alkenes using inexpensive and easy-to-handle difluoroacetic anhydride(DFAA)/pyridine N-oxide reagent system.A variety of ...
关键词:NICKEL DIFLUOROMETHYLATION Difluoroacetic anhydride Decarboxylative ALKENES 
Modular Access to Chiral 1,3-Substituted Fragments via Nickel-Catalyzed Arylboration Reaction
《Chinese Journal of Chemistry》2025年第3期261-267,共7页Yang Bao Tong Yao Weiyu Kong Yangyang Li Ying Fu Dong Wu Guoyin Yin 
supported by Guangdong Basic and Applied Basic Research Foundation(2024A1515011689).
Chiral 1,3-substituted fragments are ubiquitous in pharmaceutical molecules and natural products,prompting the development of numerous methods to access these structures.Nonetheless,devising synthetic routes for compl...
关键词:ALKENES Nickel Chiral 1 3-bis(boronates) Chain-walking Carboboration ENANTIOSELECTIVITY 
Nickel-catalyzed reductive formylation of aryl halides via formyl radical
《Chinese Chemical Letters》2024年第12期448-453,共6页Xiao-Bo Liu Ren-Ming Liu Xiao-Di Bao Hua-Jian Xu Qi Zhang Yu-Feng Liang 
financial support from the National Natural Science Foundation of China(No.22001147);Taishan Scholars Project of Shandong Province(No.tsqn202103027);Distinguished Young Scholars of Shandong Province(Overseas)(No.2022HWYQ-001);Qilu Youth Scholar Funding of Shandong University。
Aromatic aldehydes are the most fundamentally important compounds used in organic synthesis.The development of new synthetic methods for introduction of a formyl group into an organic scaffold is highly desirable.In t...
关键词:NICKEL FORMYLATION RADICAL SET Reductive coupling 
Stereoselective Synthesis of C-Vinyl Glycosides via Nickel-Catalyzed Cross-Electrophile Couplings of 1,2-Glycosyl Orthoesters and Vinyl Halides
《Chinese Journal of Chemistry》2024年第23期3029-3034,共6页Xin Wang Anrong Chen Shiyin Zhao Qiang Tao Bo Yang Xing Zhang Feng Zhu 
sponsored by the National Key R&D Program of China(Grant No.2023YFA1508800);National Natural Science Foundation of China(Grant No.22301178);Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(Grant No.21TQ1400210);Fundamental Research Funds for the Central Universities(Grant No.22x010201631);the Open Grant from the Pingyuan Laboratory(2023PY-OP-0102);Excellent Young Scientists Fund Program(Overseas);Natural Science Foundation of Shanghai(Grant No.21ZR1435600).
A highly stereoselective nickel-catalyzed cross-electrophile coupling of readily accessible,novel,stable oxygen-based glycosyl radical precursors,specifically 1,2-glycosyl orthoesters,is developed.This approach offers...
关键词:Glycosylation Nickel catalysis Cross-electrophile couplings 1 2-Glycosyl orthoesters C-C coupling STEREOCHEMISTRY 
Earth-Abundant Nickel-Catalyzed Asymmetric Hydrogenation
《Chinese Journal of Chemistry》2024年第23期3135-3156,共22页Peng Wang Zhao-Lin He Zi-Fei Xia Jun Wei Xiu-Qin Dong 
financial support from National Natural Science Foundation of China(22071187,22271226);Natural Science Foundation of Hubei Province(2021CFA069);National Youth Talent Support Program。
Transition metal-catalyzed asymmetric hydrogenation is an efficient and direct synthetic method to access chiral compounds,which features simplicity,easy working-up process,and high atomic economy.It typically relies ...
关键词:Transition metal Nickel HYDROGENATION ENANTIOSELECTIVITY Asymmetric catalysis Earth-abundant metal 
Redox-Neutral Nickel-Catalyzed Selective Hydroalkynylation of Internal Alkyne and Its Application in Anticancer Agent Discovery
《Chinese Journal of Chemistry》2024年第24期3317-3323,共7页Weiming Chen Teng Liu Shuqing Li Guangyu Li Gaorong Wu Youjia Gao Zhilin Xu Yitao Wu Xiaopeng Peng Jiuzhong Huang 
supported by the National Natural Science Foundation of China(22361003,82260676);Talent Project of Jiangxi Province(jxsq2019101065);the Jiangxi Provincial Natural Science Foundation(20224BAB216005,20232BAB216131);the Science and Technology Projects of Ganzhou(202101094462,2023PNS26854);The Start-up Fund of Gannan Medical University.
Herein,an unprecedented nickel-catalyzed regioselective hydroalkynylation of unsymmetrical internal alkynes was realized with steric hindered resistance selectivity via the cyano-directing group strategy.Significantly...
关键词:Directing group strategy Hydroalkynylation 1 3-Enynes Dihydroindeno[2 1-c]pyrazole Anti-tumor candidate 
Nickel-catalyzed regiodivergent syn-hydrosilylation of disubstituted alkynes
《Science Bulletin》2024年第21期3334-3339,共6页Jixin Wang Jie Lin Zhili Cui Jianlin Yao Konstantin Karaghiosoff Jie Li 
supported by the National Natural Science Foundation of China(22322108);Natural Science Foundation of Jiangsu Province(BK20231521 and BK20221355);Jiangsu Specially Appointed Professors Plan(SR10900122),and start-up funds from Soochow University.
Given the importance of alkenylsilanes in organosilicon chemistry and material science, direct transition-metal-catalyzed selective hydrosilylation of alkynes with hydrosilanes has emerged as apowerful platform for ac...
关键词:CATALYZED ALKYNES SUBSTITUTED 
Construction of remote cyano-substituted quaternary carbon centers via nickel-catalyzed migratory hydrocyanation of unconjugated dienes
《Science China Chemistry》2024年第10期3397-3405,共9页Yidan Xing Rongrong Yu Mingdong Jiao Ting Wang Xianjie Fang 
the National Natural Science Foundation of China(22278265,U22B20137 and 22203069);the Zhejiang Provincial Natural Science Foundation of China(LR24B020002);the start-up funding from Hangzhou Normal University(4095C50222204165 and 4095C50223204074);the Interdisciplinary Research Project of Hangzhou Normal University(2024JCXK04)for financial support of this research。
The transition-metal-catalyzed migratory functionalization has emerged as a robust protocol for the building of C–C bonds remote from the“initiation”position.However,a similar strategy for the construction of quate...
关键词:chain-walking regioselectivity remote cyanation quaternary carbon centers unconjugated dienes 
Nickel-catalyzed arylcyanation of alkenes via cyano group translocation:access to 1,n-dinitriles or 4-amino nitriles
《Science China Chemistry》2024年第9期2975-2981,共7页Xiaohong Li Shenfan Wang Xiangxiang Fu Donghui Xing Zeyuan Fu Yuanfu Deng Huanfeng Jiang Liangbin Huang 
supported by the National Natural Science Foundation of China(21971074,22001076);the Natural Science Foundation of Guangdong Province(2022A1515010660,2021A1515220024);the Natural Science Foundation of Guangzhou(202102020982)。
Herein,a nickel-catalyzed arylcyanation of unactivated alkenes via cyano group translocation with aryl boronic acids has been developed.These transformations provided a robust approach to constructing structurally div...
关键词:arylcyanation nickel catalysis cyano group translocation 1 n-dinitriles 4-amino nitriles 
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