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FORMYLATION: 作品数：21被引量：20H指数：3; 导出分析报告; 相关领域：理学更多>>; 相关期刊：《Open Journal of Physical Chemistry》《Science China Chemistry》《Open Journal of Inorganic Chemistry》《Chinese Journal of Structural Chemistry》更多>>; 相关基金：国家自然科学基金中国博士后科学基金广东省自然科学基金清华大学自主科研计划更多>>

Nickel-catalyzed reductive formylation of aryl halides via formyl radical: 《Chinese Chemical Letters》2024年第12期448-453,共6页Xiao-Bo Liu Ren-Ming Liu Xiao-Di Bao Hua-Jian Xu Qi Zhang Yu-Feng Liang; financial support from the National Natural Science Foundation of China(No.22001147);Taishan Scholars Project of Shandong Province(No.tsqn202103027);Distinguished Young Scholars of Shandong Province(Overseas)(No.2022HWYQ-001);Qilu Youth Scholar Funding of Shandong University。; Aromatic aldehydes are the most fundamentally important compounds used in organic synthesis.The development of new synthetic methods for introduction of a formyl group into an organic scaffold is highly desirable.In t...; 关键词：NICKEL FORMYLATION RADICAL SET Reductive coupling

Transition metal-free catalytic formylation of carbon dioxide and amide with novel poly(ionic liquid)s: 《Green Synthesis and Catalysis》2022年第2期162-167,共6页Peibo Chen Xiaoyu Tang Xiujin Meng Haitao Tang Yingming Pan Ying Liang; We thank the financial support from the Guangxi Key R&D Program(No.AB18221005);the National Natural Science Foundation of China(Nos.41965006 and 52170107);the Innovation Project of GUET Graduate Education(No.2021YCXS170).; Functionalised mesoporous poly(ionic liquid)s are valuable carbon dioxide capture and conversion materials.Here,an imidazole poly(ionic liquid)PIL-s1-HCO_(3) with a mesoporous structure was formed by the copolymerisat...; 关键词：Carbon dioxide Poly(ionic liquid)s Heterogeneous catalysis FORMYLATION

Rational design and precise manipulation of nano‐catalysts被引量：1: 《Chinese Journal of Catalysis》2022年第4期898-912,共15页Qinggang Liu Junguo Ma Chen Chen; 国家重点研发计划(2016YFA0202801,2017YFA0700101);国家自然科学基金(21925202,21872076,22008136);北京自然科学基金(JQ18007);清华大学自主科研计划资助。; Nano‐catalysis plays a vital role in the chemical transformations and significantly impacts the booming modern chemical industry.The rapid technological enhancements have resulted in serious energy and environmental ...; 关键词：Nano‐catalysis Single‐atom catalysts Water splitting Oxygen reduction reaction CO_(2)reduction reaction Silane oxidation Benzene oxidation N‐formylation

Base-Promoted Formylation and N-Difluoromethylation of Azaindoles with Ethyl Bromodifluoroacetate as a Carbon Source: 《Chinese Journal of Chemistry》2021年第6期1477-1482,共6页Yang Li Ning Sun Cai-Lin Zhang Meng Hao; the financial support from the National Natural Science Foundation of China(No.21503161);the Key Research&Development Project in Shaanxi Province(No.2017ZDXM-GY-040);the Doctoral Scientific Research Foundation of Xi'an Polytechnic University(No.107020336).; We reported for the first time that ethyl bromodifluoroacetate directly reacts with azaindole without transition metal catalysis to produce a difluoromethyl protected 5-aldehyde group product in one step.It is worth m...; 关键词：AZAINDOLES C1 building blocks DIFLUOROMETHYLENE Hydrolysis Synthetic methods

Zinc Powder Catalysed Formylation and Urealation of Amines Using CO2 as a C1 Building Block被引量：1: 《Chinese Journal of Chemistry》2020年第10期1057-1064,共8页Chongyang Du Yaofeng Chen; We acknowledge financial support from the National Natural Science Foundation of China(Nos.21732007 and 21821002);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);Fujian Institute of Innovation,Chinese Academy of Sciences.; Summary of main observation and conclusion Transformation of CO2 into valuable organic compounds catalysed by cheap and biocompatible metal I catalysts is one of important topics of current organic synthesis and catal...; 关键词：AMINES AROMATIC MIXTURE

Synthesis of Intermediate N-Chloroformyl-N-[4-(trifluoromethoxy)phenyl]Methyl Carbamate of Indoxacarb: 《Plant Diseases and Pests》2020年第1期36-40,共5页Zhang Zhenming Kong Xianbin Wang Gang Wang Xiaohui Liu Minjin; [Objective]The paper was to study a synthetic method suitable for industrial production of intermediate N-Chloroformyl-N-[4-(trifluoromethoxy)phenyl]methyl carbamate of indoxacarb.[Method]Using 4-trifluoromethoxy anil...; 关键词：INDOXACARB INTERMEDIATE N-chloroformyl-N-[4-(trifluoromethoxy)phenyl]methyl CARBAMATE Synthesis Sodium/potassium ammonium salt FORMYLATION Recrystallization

Amine formylation with CO2 and H2 catalyzed by heterogeneous Pd/PAL catalyst被引量：8: 《Chinese Journal of Catalysis》2019年第8期1141-1146,共6页Xingchao Dai Bin Wang Aiqin Wang Feng Shi; supported by the National Natural Science Foundation of China(91745106,21633013);the Major Projects of the National Natural Science Foundation of Gansu,China(18JR4RA001);the Youth Innovation Promotion Association CAS(2019409);Fujian Institute of Innovation,CAS and Key Research Program of Frontier Sciences of CAS(QYZDJ-SSW-SLH051)~~; For the first time, Pd supported on natural palygorskite was developed for amine formylation with CO2 and H2. Both secondary and primary amines with diverse structures could be converted into the desired formamides at...; 关键词：FORMYLATION Carbon dioxide AMINE Heterogeneous palladium catalyst FORMAMIDE

Preparation of Single Substituted Phenyl Porphyrins Form <i>Meso</i>-Tetraphenyl Porphyrin-Synthetic Example from Symmetric Porphyrin into Asymmetric Porphyrins: 《Open Journal of Inorganic Chemistry》2018年第1期21-27,共7页Hui Lin Xiaoting Chen Yahong Wu Shanling Tong Sheng Hu Jian Yu Yan Yan; Two asymmetric porphyrins, 5-(4-chloromethylphenyl)-10, 15, 20-triphenyl porphyrin and 5-(4-formylphenyl)-10, 15, 20-triphenyl porphyrin, were successfully prepared by the symmetric meso-tetraphenyl porphyrin and rela...; 关键词：ASYMMETRIC PORPHYRIN Spectral Characterization Redox CHLOROMETHYLATION FORMYLATION

Zinc phthalocyanine as an efficient catalyst for halogen-free synthesis of formamides from amines via carbon dioxide hydrosilylation under mild conditions被引量：3: 《Chinese Journal of Catalysis》2017年第8期1382-1389,共8页Rongchang Luo Xiaowei Lin Jing Lu Xiantai Zhou Hongbing Ji; supported by the National Natural Science Foundation of China (21676306,21425627);the National Key Research and Development Program of China (2016YFA0602900);the Natural Science Foundation of Guangdong Province (2016A030310211);the Characteristic Innovation Project (Natural Science) of Guangdong Colleges and Universities~~; The combination of a zinc phthalocyanine(ZnPc)catalyst and a stoichiometric amount of dimethyl formamide(DMF)provided a simple route to formamide derivatives from amines,CO2,and hydrosilanes under mild conditions.We d...; 关键词：Carbon dioxide Zinc phthalocyanine Cooperative effect N‐formylation HYDROSILANES

Na Y zeolite functionalized by sulfamic acid/Cu(OAc)_2 as a new and reusable heterogeneous hybrid catalyst for efficient solvent-free formylation of amines: 《Chinese Chemical Letters》2017年第8期1767-1772,共6页Samira Kazemi Akbar Mobinikhaledi Mojgan Zendehdel; Arak University for financial support for this work; NaY zeolite functionalized by sulfamic acid/Cu（OAc）_2[NaY/SA/Cu（Ⅱ）] was synthesized and used as a new,efficient and recyclable catalyst for preparation of formamides. This novel organic-inorganic hybrid catalyst ...; 关键词：Heterogeneous catalyst NaY/SA/Cu（Ⅱ） Formylation Formamides Zeolite

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