HETEROARENE

作品数：6被引量：2H指数：1
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Rapid Access to Acylation and Alkylation of N-Heteroarenes Using Ester Acetates as Reactants
《Chemical Research in Chinese Universities》2024年第6期1212-1219,共8页XU Jianxiong HUANG Weimin LI Jizhen 
supported by the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization,China (No.RERU2023006).
The laboratory-abundant and low-toxic ethyl acetate was explored successfully for the first time as acyl group donor for the Minisci-type acylation of quinolines.In this approach,TBAC/K_(2)S_(2)O_(8) (TBAC: tert-butyl...
关键词：Ethyl acetate ACYLATION Chlorine radical N-Heteroarene Minisci-type 
Sigmatropic rearrangements of B(MIDA)-propargylic alcohols towards the diverse synthesis of α-functionalized organoborons
《Science China Chemistry》2024年第2期568-575,共8页Jiasheng Qian Li-Cai Liu Zhi-Hao Chen Yuan Liu Yin Li Qingjiang Li Honggen Wang 
supported by the National Natural Science Foundation of China (22022114,21971261);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01Y093);Guangdong Basic Research Center of Excellence for Functional Molecular Engineering。
α-Functionalized organoborons are useful building blocks and key structural elements in functional molecules.Their previous synthesis relied on the famous Matteson reaction or the late-stage borylative modification o...
关键词：ORGANOBORON diverse synthesis sigmatropic rearrangement HETEROARENE AMIDE 
Copper-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides withβ-trifluoromethyl-substituted alkenyl heteroarenes
《Science China Chemistry》2023年第11期3193-3204,共12页Xiang Cheng Xin Chang Yuhong Yang Zongpeng Zhang Jing Li Yipu Li Wenxiao Zhao Lung Wa Chung Huailong Teng Xiu-Qin Dong Chun-Jiang Wang 
supported by the National Natural Science Foundation of China(22071186,22071187,22073067,22101216,22271226,21933003,22193020,22193023);the National Youth Talent Support Program;the Natural Science Foundation of Hubei Province(2020CFA0362021CFA069);the Fundamental Research Funds for the Central Universities(2042022kf1180,2042022kf1040);the Shenzhen Nobel Prize Scientists Laboratory Project(C17783101);the Guangdong Provincial Key Laboratory of Catalytic Chemistry(2020B121201002)。
Copper-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides andβ-trifluoromethyl-substituted alkenyl heteroarenes was developed for the first time.A wide range of enantioenriched pyrrolidines containin...
关键词：asymmetric catalysis 1 3-dipolar cycloaddition chiral pyrrolidines HETEROARENE trifluoromethyl group 
Enhancing Photovoltaic Performance of Ladder-Type Heteroarene-Based Electron Acceptors by Modulating Molecular Packing被引量：1
《Chinese Journal of Chemistry》2023年第17期2143-2150,共8页Hongxin Tao Changquan Tang Yunlong Ma Shu-Quan Zhang Ruochuan Liao Qisheng Tu Qingdong Zheng 
supported by the National Natural Science Foundation of China(Nos.52130306,22075287);the Program of Youth Innovation Promotion Association CAs(No.2021299).
Comprehensive Summary,The development of novel building blocks with sp3-hybridized-carbon-free conjugated skeletons is important to further advance and enrich nonfullerene acceptors(NFAs),but this remains a challenge ...
关键词：Polymer solar cells Electron acceptors Noncovalent interactions Molecular packing Electron transport 
Synthesis,Structure,and Optical-response Magnetic Property of a Heteroarene-azo Functionalized Mn_(19) Cluster被引量：1
《Chinese Journal of Chemistry》2023年第14期1667-1672,共6页Yongkai Deng Yingying Wu Zhaoyang Li Zvonko Jagličić Rakesh Kumar Gupta Chenho Tung Di Sun 
financially supported by the National Natural Science Foundation of China(Grant Nos.52261135637,22171164);the Natural Science Foundation of Shandong Province(No.ZR2022QB191);the Taishan Scholar Project of Shandong Province of China(Nos.tsqn201812003 and ts20190908);the Instrument Improvement Funds of Shandong University Public Technology Platform(No.ts20220102);the Slovenian Research Agency(Grant No.P2-0348).
Metal clusters with photoswitching ligands can undergo magnetic changes under light radiation,which makes them potential optical-response magnetic-switching materials.Herein,a photoswitchable Mn-oxo cluster[Mn^(II)_(1...
关键词：CRYSTALSTRUCTURE Cluster compounds PHOTOCHROMISM Magnetic properties Stimuli-responsive molecular magnet 
Seeing Is Believing:A Wavy N-Heteroarene with 20 Six-Membered Rings Linearly Annulated in a Row
《CCS Chemistry》2022年第11期3491-3496,共6页Zhongbo Zhang Zilong Wang Naoki Aratani Xiaozhang Zhu Qichun Zhang 
The work at NAIST was supported by Grant-in-Aid for Scientific Research No.JP20H02711(NA).
Structurally well-defined arenes with higher numbers of linearly-fused six-member rings(n≥10)are important and highly desirable not only because of their experimental challenges but also due to their fundamental inte...
关键词：N-heteroarenes single-crystal structure linear annulation optical properties 
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