DEAROMATIZATION

作品数:45被引量:22H指数:3
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相关领域:理学更多>>
相关机构:广西师范大学嘉兴学院苏州大学更多>>
相关期刊:《Science Bulletin》《Green Synthesis and Catalysis》《Petroleum Science》《Chinese Journal of Catalysis》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金福建省自然科学基金更多>>
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Tandem asymmetric dearomatized functionalization reaction of phenols with Evans-ynamides enabled by divergent electrophiles
《Science China Chemistry》2025年第2期649-660,共12页Ying-Qi Zhang Gan-Lu Qian Yun Liu Jia-Hui Li Xin Hong Zhou Xu Bo Zhou Long-Wu Ye 
supported by the National Natural Science Foundation of China(22125108 and 22121001 for Ye LW,22122109 and 22271253 for Hong X);the National Key R&D Program of China(2022YFA1504301,Hong X);the Zhejiang Provincial Natural Science Foundation of China(LDQ23B020002,Hong X);the Starry Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study(SNZJU-SIAS-006,Hong X);the Beijing National Laboratory for Molecular Sciences(BNLMS202102,Hong X);the CAS Youth Interdisciplinary Team(JCTD-2021-11,Hong X);the Fundamental Research Funds for the Central Universities(226-2022-00140,226-2022-00224,and 226-2023-00115,Hong X);the State Key Laboratory of Physical Chemistry of Solid Surfaces(202210,Hong X);the Leading Innovation Team grant from the Department of Science and Technology of Zhejiang Province(2022R01005,Hong X);the Natural Science Foundation of Jiangsu Province(BK20211059);National Found for Fostering Talents of Basic Science(NFFTBS,J1310024).
Herein,we disclose a highly regio-/chemoselective tandem asymmetric dearomatized halofunctionalization reaction of phenoltethered ynamides with diverse electrophilic halogenation sources in a catalyst-free manner for ...
关键词:ALKYNES cyclization DEAROMATIZATION Evans chiral auxiliary SPIROCYCLES 
Enantioselective copper-catalyzed dearomative borylative cyclization of indoles and mechanistic insights
《Science China Chemistry》2025年第2期670-678,共9页Yanfei Li Xuetao Li Zheng Zhang Yiliang Zhang Xiuping Yuan Jianjun Yin Simin Wang Wei Guan Qian Zhang Tao Xiong 
supported by the Natural Science Foundation of Jilin Province(20210101134JC);the National Natural Science Foundation of China(22171042,21831002,22193012);the Fundamental Research Funds for the Central Universities.
Alicyclic nitrogen heterocycles,such as enantioenriched polycyclic fused[1,2-a]indoline derivatives,are widespread in natural products,agrochemicals and pharmaceutical agents.Existing methods predominantly rely on the...
关键词:copper catalysis DEAROMATIZATION borylative cyclization INDOLES DFT calculations 
Total synthesis of(+)-taberdicatine B and(+)-tabernabovine B
《Chinese Chemical Letters》2025年第2期321-325,共5页Tengfei Xuan Xinyu Zhang Wei Han Yidong Huang Weiwu Ren 
the Qingdao Marine Science and Technology Center(No.2022QNLM030003-2);the Fundamental Research Funds for the Central Universities,Taishan Scholar Program of Shandong Province(No.tsqn202103152);National Natural Science Foundation of China(No.22171251) for financial support。
The first total synthesis of(+)-taberdicatine B and(+)-tabernabovine B has been accomplished in 10steps with 26.9% overall yield and 15 steps with 7.3% overall yield,respectively.The prominent features of this efficie...
关键词:Taberdicatine B Tabernabovine B Hexahydropyrrolo[2 3-b]indole Asymmetric dearomatization Total synthesis 
A Machine Learning Model for Predicting Enantioselectivity in Hypervalent Iodine(III)Catalyzed Asymmetric Phenolic Dearomatizations
《CCS Chemistry》2024年第10期2515-2528,共14页Ben Gao Liu Cai Yuchen Zhang Huaihai Huang Yao Li Xiao-Song Xue 
supported by the Ministry of Science and Technology of China(grant no.2021YFF0701700);the National Natural Science Foundation of China(grant nos.22122104,22193012,and 21933004);the CAS Project for Young Scientists in Basic Research(grant nos.YSBR-052 and YSBR-095);the Strategic Priority Research Program of the Chinese Academy of Sciences(grant no.XDB0590000).
Catalytic asymmetric dearomatization(CADA)of phenols has emerged as a powerful strategy for constructing stereochemically complicated architectures from planar aromatic feedstocks.However,the development of novel cata...
关键词:machine learning chiral hypervalent iodine CATALYSIS DEAROMATIZATION ENANTIOSELECTIVITY 
Copper-catalyzed asymmetric dearomatizing amination of 2-naphthols:Csp^(2)–N coupling via 1,3-reductive elimination
《Science China Chemistry》2024年第8期2694-2700,共7页Aying Yihuo Maoping Pu Zheng Tan Jibang Liao Jiuqi Tan Qi-Lin Zhou Xiaohua Liu Xiaoming Feng 
supported by the National Natural Science Foundation of China(22188101);Sichuan Science and Technology Program(2021YJ0561)。
An efficient catalytic asymmetric dearomatizing amination of 2-naphthols and phenols catalyzed by N,N′-dioxide-copper(I)complex as a chiral catalyst was presented.A variety of optically activeβ-naphthalenone compoun...
关键词:asymmetric catalysis AMINATION DEAROMATIZATION copper catalysis coupling reaction 
Divergent Synthesis of Primary Amides via Modular Dearomative Carbamoylations of Areneπ-Systems
《CCS Chemistry》2024年第8期2066-2074,共9页Chu-Qiao Li Xu Jiang Ming-Yang Wang Wei-Long Zeng Wei Li 
the National Natural Science Foundation of China(grant no.22271251);the Fundamental Research Funds for the Central Universities(grant nos.226-2023-00016,226-2023-00115,and 226-2022-00224).
In sharp contrast to the well researched and well developed aminocarbonylation of alkenes,the dearomative carbamoylation of abundant areneπ-systems has scarcely been studied despite its great potential to enrich the ...
关键词:AMINOCARBONYLATION ARENE CARBAMOYLATION DEAROMATIZATION primary amide 
Photocatalytic Site-Selective Cascade Radical Addition of Biaryl Ynones for the Construction of Spiro-and Fused Carbon Rings
《Chinese Journal of Chemistry》2024年第14期1599-1605,共7页Kairui Liu Chunhang Zhao Liji Gu Xiang Li Jiali Yan Siqi Lao Weiwei Huan Yan Zhang 
the Natural Science Foundation of Zhejiang Province(LY22B020001);the Zhejiang Public Welfare Public Research Program(LGC22B010001);the National Natural Science Foundation of China(32201238)is greatly acknowledged.
Functionalized free radical addition/cyclization reactions represent an efficient way for introducing new functionality or coupling fragments to molecules.Ynones are good regional selectivity radical acceptors in orga...
关键词:YNONES Photocatalysis Cascade cyclization Alkoxycarbonyl radical DEAROMATIZATION BIARYLS Regioselectivity Radical reactions 
Catalyst-free electrochemical dearomatization of pyridine derivatives
《Green Synthesis and Catalysis》2024年第2期136-139,共4页Kui Wang Yingjun Tian Baoying Li Ling Wang Wei Gao Xiaofei Jia Ruiming Wang Yanping Zhu Jianbin Chen 
the National Natural Science Foundation of China(Nos.22171154 and 21801144);the Youth Innovative Talents Recruitment and Cultivation Program of Shandong Higher Education,the Natural Science Foundation of Shandong Province(Nos.ZR2020QB114 and ZR2020QB008);Jinan Science&Technology Bureau(No.2021GXRC080);supported by the Foundation(No.ZZ20190312)of State Key Laboratory of Biobased Material and Green Papermaking,Qilu University of Technology(Shandong Academy of Sciences);the Program for Scientific Research Innovation Team in Colleges and Universities of Shandong Province,the Open Fund of the Department of Chemistry,Qingdao University of Science and Technology(No.QUSTHX202010);Science and Technology Innovation Development Plan of Yantai(No.2020MSGY114);Yantai“Double Hundred Plan”.
We demonstrated herein an electrochemical dearomatizative alkylation of Katritzky salts,wherein Katritzky salts were harnessed as both radical acceptors and donors.A wide range of privileged dihydropyridine scaffolds ...
关键词:DEAROMATIZATION ELECTROSYNTHESIS Katritzky salts Dihydropyridine 
Electrochemical Dearomative Spirocyclization of N-Acyl Sulfonamides in a Continuous-Flow Cell
《Chinese Journal of Chemistry》2024年第9期980-984,共5页Ting Liu Zhaojiang Shi Yaofeng Yuan Yuqi Lin Ke-Yin Ye 
supported by the National Natural Science Foundation of China(No.22171046);the Hundred-Talent Project of Fujian(No.50021113).
The development of efficient and sustainable methods to obtain spirocyclic compounds is of significance as these structures are widely found in pharmaceuticals and agrochemicals.Herein,we disclose an electrochemical d...
关键词:Electrochemistry CONTINUOUS-FLOW DEAROMATIZATION SPIROCYCLIZATION SULFONAMIDES CYCLIZATION Methodology and reactions 
Catalytic asymmetric dearomative azo-Diels–Alder reaction of 2-vinlyindoles
《Chinese Chemical Letters》2024年第4期357-362,共6页Yu-Hang Miao Zheng-Xu Zhang Xu-Yi Huang Yuan-Zhao Hua Shi-Kun Jia Xiao Xiao Min-Can Wang Li-Ping Xu Guang-Jian Mei 
the generous financial support from Natural Science Foundation of Henan Province (No.222300420084);application research plan of Key Scientific Research Projects in Colleges and Universities of Henan Province (No.22A150056);the Youth Innovation Team Program in Colleges and Universities of Shandong Province (No.2022KJ228);National Natural Science Foundation of China (No.22208302)。
Due to the high electrophilic nature of azo-dienophiles, azo-Diels–Alder proceeds rapidly even without the need of a catalyst and is therefore regarded as the “click reaction”. This spontaneity causes strong backgr...
关键词:Catalytic asymmetric dearomatization Azo-Diels–Alder reaction 2-Vinylindoles Chiral phosphoric acid Tetracyclic indole derivatives 
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