P450 enzymes-catalyzed aromatic hydroxylation plays an important role in detoxification,biosynthesis,and potential carcinogenic effect of aromatic compounds.Though it has been explored for decades,the actual process o...
supported by the National Natural Science Foundation of China(22471182,22271201,92056116,22422108,22171194,22201194);the Fundamental Research Funds for the Central Universities(20826041D4117).
While extensive research has explored manipulating supramolecular chirality through internal and external factors,the specific solvation effect remains uncharted territory.This study synthesized ortho-functionalized p...
Macrocyclic arenes have become an important tool in supramolecular chemistry due to their special structure,easy functionalization and prominent host–guest properties.The design and synthesis of macrocyclic arenes wi...
financial support sponsored by the National Natural Science Foundation of China(92356307);financial support sponsored by the National Natural Science Foundation of China(92056203);financial support sponsored by the National Natural Science Foundation of China(22201077);Shanghai Pilot Program for Basic Research(TQ20240205);Natural Science Foundation of Shanghai(23ZR1419600);Science and Technology Commission of Shanghai Municipality(21520710200);the National Key R&D Program of China(2021YFA1501600)。
Aiming at the construction of novel multistate circularly polarized luminescence(CPL)switches,dual stimuli-responsive chiral[2]rotaxanes towards anions and light have been designed and constructed.Through the light-co...
financial supports from National Natural Science Foundation of China(No.22204169);Gansu Natural Science Foundation(Nos.23JRRA619,21JR7RA076);Scientific and Technological Program of Chengguan District,Lanzhou(No.2023JSCX0037)。
A novel amine-modified pillar[5]arene bonded porous silica adsorbent(DETA-P5S)was designed to be applied to dynamic CO_(2)adsorption and selective separation of CO_(2)over N_(2)and CH_(4)gases mixture.The results demo...
supported by the National Natural Science Foundation of China(21901145,22171165,22371170);the financial support from the Youth Cross-Scientific Innovation Group of Shandong University。
Unveiling the role of weak non-covalent forces in chiral self-assembly is pivotal in the design and fabrication of functional chiroptical materials.The nature of arene-perfluoroarene(AP)force is the electrostatic attr...
supported by the NSFC(Nos.22065031,22061039,22001214,22165027);the Fundamental Research Funds for the Central Universities(No.31920230145);the Top-Notch Talent Project in Gansu Province,the Key R&D Program of Gansu Province(No.21YF5GA066);Gansu Province College Industry Support Plan Project(No.2022CYZC-18);Natural Science Foundation of Gansu Province(Nos.2020-0405-JCC-630,20JR10RA088,21JR1RA220);Gansu Province Science Foundation for Youths(23JRRA690);Northwest Normal University Young Scholars Research Capacity Improvement Program(NWNU-LKQN2023-05).
The cyanide anion(CN^(–))is known to be one of the most toxic anions.Therefore,there is an urgent need to develop a reliable,sensitive,selective,rapid and effective method for the detection of CN^(–).Here,a self-ass...
financially supported by the National Natural Science Foundation of China(Nos.22001214,21662031,21661028,22061039);the Science Fund for Distinguished Young Scholars of Gansu Province(No.22JR5RA131);the Longyuan Innovation and Entrepreneurship Talent Project of Gansu Province;the Major Project Cultivation Program of Northwest Normal University(No.NWNU-LKZD2022-01);the Top Leading Talents Project of Gansu Province,the Key R&D Program of Gansu Province(No.21YF5GA066);Gansu Province College Industry Support Plan Project(No.2022CYZC-18)。
Oligo[n]rotaxanes are one of the most extensively studied categories of mechanically bonded macromolecules.In this study,a supramolecular oligo[2]rotaxane is successfully constructed driven by platinum(Ⅱ)metallacycle...
the financial support from the“Young Talent Support Plan”(no.050700-71240000000046)of Xi’an Jiaotong University;the Natural Science Foundation of Shaanxi Province(no.2021JM-006);the“Young Talent Start-up Fund”Project of Zhengzhou University(no.32212778);the Joint Project from the Henan Provincial and the China National Natural Science Foundations(no.U2004208);the Ministry of Education Singapore under its Academic Research Funds(no.RG3/21,RG2/22,and RG85/22);the Agency for Science,Technology and Research(A*STAR)Singapore through its Manufacturing,Trade and Connectivity(MTC)Individual Research Grant(no.M21K2c0105)
The development of active water oxidation catalysts for water splitting has stimulated considerable interest.Herein,the design and building of single atom Co sites using a supramolecular tailoring strategy are reporte...
supported by the National Natural Science Foundation of China(Nos.32101215,22007052);Natural Science Foundation of Jiangsu Province(Nos.BK20180942,BK20190917)。
Photosynthesis is the process through which living plants utilize photosynthetic pigments,such as chlorophyll,to convert CO_(2)and water into organic compounds and release O_(2)under visible light.In this study,we hav...