University of Manchester,the National Natural Science Foundation of China and BNLMS for funding,and the EPSRC for funding of the EPSRC National EPR Facility at Manchester(EP/W014532/1 and EP/X034623/1);We are grateful to the STFC/ISIS Facility and Diamond Light Source for access to the beamlines TOSCA/MAPS,and I11/B18/B22,respectively;We are grateful to the STFC/ISIS Facility and Diamond Light Source for access to the beamlines TOSCA/MAPS,and I11/B18/B22,respectively;We acknowledge the UK catalysis Hub Block Allocation Group(BAG)Programme Mode Application for provision of beamtime at B18 for collection of the data presented in this work and the initial discussion of the data;The UK Catalysis Hub is kindly thanked for resources and support provided via our membership of the UK Catalysis Hub Consortium and funded by EPSRC grant:EP/R026939,EP/R026815,EP/R026645,EP/R027129 and EP/M013219(biocatalysis);We acknowledge the support of The University of Manchester's Dalton Cumbrian Facility(DCF),a partner in the National Nuclear User Facility;We recognise Dr.R.Edge for the assistance during the 60Co-irradiation processes;We thank M.Kibble for help at ISIS beamlines;TEM access was supported by the Henry Royce Institute for Advanced Materials,funded through EPSRC grants EP/R00661X,EP/S019367,EP/P025021 and EP/P025498;Zhaodong Zhu thanks the President's Doctoral Scholar award of University of Manchester for funding;Meng He and Lutong Shan thank the China Scholarship Council(CSC)for funding.
The methanol-to-olefins(MTO)process has the potential to bridge future gaps in the supply of sustainable lower olefins.Promoting the selectivity of propylene and ethylene and revealing the catalytic role of active sit...
This Highlight is inspired by a recent article in Science in which Gong and co-workers from Tianjin University reported a discovery of defective TiOx overlayers on metallic Ni nanoparticles induced by strong metal-sup...
supported by National Natural Science Foundation of China(22175193,22261132517,22108286),QIBEBT(S202306);Shandong Provincial Natural Science Foundation(ZR2021MB058).
Propylene is an important feedstock for polymer production.The greater abundance of propane in shale gas has led to a switch in the industrial feedstocks for propylene from naphtha to propane[1].Catalytic dehydrogenat...
supported by the National Natural Science Foundation of China(Nos.22278451 and 21938001);Guangdong Basic and Applied Basic Research Foundation(2022B1515120057,2019A1515110979)
The development of green route for preparing propylene oxide(PO)with molecular oxygen is of significance both in academic and industrial.In this work,propylene epoxidation coupled with furfural oxidation catalyzed by ...
supported by the National Natural Science Foundation of China (22071194, 22371225, 21971207);Shenzhen Science and Technology Program (KCXFZ20211020163818026);supported by the U.S. Department of Energy, Basic Energy Sciences, Division of Materials Sciences and Engineering (DE-SC0019902)。
Selective adsorption of paraffins over olefins(mostly C2 and C3) by porous solids could offer tremendous advantages for the purification of olefins, which is, however, challenging as it has stringent requirements on t...
supported by the National Key Research and Development Program of China (2022YFE0208300);the National Natural Science Foundation of China (22078354, 22108290)。
The application of non-noble metal catalysts in the catalytic direct gas-phase epoxidation of propylene with H2and O2to produce propylene oxide is valuable and challenging. The introduction of alkali metal promoters i...
Dispersing metals from nanoparticles into clusters or single atoms often exhibits unique properties such as the inhibition of structure-sensitive side reactions.Here,we reported the use of ion exchange(IE)methods and ...
supported by the China Postdoctoral Science Foundation(2022M722213);GuangDong Basic and Applied Basic Research Foundation(2023A1515110415).
Per-and polyfluoroalkyl substances(PFASs)constitute a broad group of fluorinated organic chemicals that are widely used in consumer products and industrial applications due to their excellent physicochemical propertie...
The olefins industry is a cornerstone of the global chemical industry and plays a key role in the economy[1].Propane dehydrogenation(PDH)is an on-purpose technology for propylene synthesis.Heterogeneous commercial cat...
Supported by National Key Research and Development Program of China(2022 YFB 3704700(2022 YFB 3704702));Major Scientific and Technological Innovation Project of Shandong Province(2021 CXGC 010901);Taishan Scholar Program。
Heterogeneous TiCl4/MgCl_(2) type Ziegler-Natta(Z-N)catalysts with unique advantages like low cost,high activity,high stereoregularity and pretty particle morphology,contribute to more than 130 Mt polyolefin large-sca...