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the support from National Key R&D Program of China (2021YFC2103704);the National Natural Science Foundation of China (22222808);the Natural Science Foundation of Shandong Province (ZR2023QB152);the Youth Innovation Team Plan of Shandong Province (2022KJ270);the China National Postdoctoral Program for Innovative Talents (BX20240251);the Aeronautical Science Foundation of China (2023Z073048003);the Haihe Laboratory of Sustainable Chemical Transformations。
Photoinduced[2+2]cycloaddition of biomass-derived cycloolefin is a promising approach to synthesize high-energy bio-fuels,however,the conversion efficiency and selectivity are still low.Herein,we provide an acid-promo...
supported by the National Natural Science Foundation of China(Nos.22371272 and 22301295);the Fundamental Research Funds for the Central Universities(Nos.YD2060002036 and WK5290000004);International Partnership Program of the Chinese Academy of Sciences(No.123GJHZ2022064MI);the Collaborative Innovation Program of Hefei Science Center,CAS(No.2022HSC-CIP014)。
Single-chain nanoparticles represent an emerging class of nanomaterials designed to mimic protein's folding paradigm.Intrachain covalent crosslinking toward the formation of single-chain nanoparticles encounters compl...
supported by the National Natural Science Foundation of China (22271203);the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry(KF2021005);the Collaborative Innovation Center of Suzhou Nano Science and Technology;the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)。
In natural and artificial systems,reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive the forward and backward processes.In applications for which switchin...
supported by the Beijing Natural Science Foundation(No.2192004).
A photocycloaddition reaction of ethyl 1,4-diaryl-1,4-dihydropyridine-3-carboxylate for the construction of 3,9-diazatetraasteranes(Pr)and 3,9-diazatetracyclododecanes(P2)is reported for the first time.The types of re...
Financial support from the National Natural Science Fund for Distinguished Young Scholars of China(grant no.22025107);the National Youth Top-notch Talent Support Program of China,the Key Science and Technology Innovation Team of Shaanxi Province(grant nos.2019TD-007 and 2019JLZ-02);the FM&EM International Joint Laboratory of Northwest University is gratefully acknowledged.
Supramolecular interactions can help recognize and organize substrates around an enzyme’s active sites and subsequently assemble a new molecule in a certain way.Inspired by nature’s control of reactions,in this work...
financially supported by the National Key Research and Development Program of China (No. 2021YFF0502400);the National Natural Science Foundation of China (Nos. 81991521, 82022069 and 42076099);the Shanghai Rising-Star Program (No. 20QA1411100);“Youth Innovation Promotion Association” of Chinese Academy of Sciences (No. Y202065);the SKLDR/SIMM Project (No. SIMM2103 ZZ-06)。
Eight polycyclic furanobutenolide-containing norcembrane diterpenoids featuring C19 frameworks(1–8)were rapidly recognized and isolated from the Hainan soft coral Sinularia sp. by the HSQC-based small molecule accura...
The development of catalytic asymmetric radical reactions is an attractive but formidable task.The high reactivity of radicals enables the use of readily accessible feedstocks and mild reaction conditions,but it leads...
the financial support from the National High Technology Research and Development Program of China(No.2005AA320030);SJTU-Aeronautics Industry Joint Program(No.0304)
Three novel bis-chalcone derivatives with different alkyldioxy spacers were synthesized and dispersed into polymethyl methacrylate (PMMA) chloroform solution with 6-nitro-1'-ethyl-3',3'-dimethylspiro-2H-1-benzopy...
The effects of reaction pathway and temperature on stereo and regio selectivity of photocycloaddition of 1, 3 dimethylthymine (DMT) which gives four cyclobutane type dimers in solution using acetone as the photosensit...
Photochemical [2+2] cycloaddition of C60 with podophyllotoxin derivative containing a cyclohexadienone group in o-dichlorobenzene afforded an isomeric mixture of adducts and a pure adduct of C60-fused podophyllotoxin ...