the National Natural Science Foundation of China(grant no.22171046);the Hundred-Talent Project of Fujian(grant no.50021113)is gratefully acknowledged.
Sulfonimidoyl fluorides,the aza-bioisostere of sulfonyl fluorides,are emerging as a promising linkage agent in the sulfur(VI)fluoride exchange reaction(SuFEx).However,conventional synthetic approaches typically requir...
financially supported by the National Natural Science Foundation of China (Nos. 51673057, 21622402, and 21574036);N. Liu thanks Anhui Provincial Natural Science Foundation (No. 1608085MB41)
We report the polymerization of phenyl isocyanides with the chiral palladium(II) initiating system. The resulting polymers with optically active properties were obtained by polymerization of the racemic isocyanide m...
Financial support from the National Natural Science Foundation of China
Simple and readily available chiral N-(sulfinyl)allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic a-keto...
Project supported by the National Natural Science Foundation of China (No. 20372048) and the Ministry of Education (EYTP).
As a versatile chiral ammonia equivalent, chiral tert-butylsulfinylamide (6) (TBSA) is a very useful auxiliary due to the characteristics of highly stereoselectivity in asymmetric induction and the sulfinyl group bein...
Since its introduction in 1997, tert-butanesulfinamide (1) has proven to an extremely versatile chiral ammonia equivalent for the asymmetric synthesis of amines[1]. However, practical methods for the preparation of en...