SULFINAMIDE

作品数:5被引量:4H指数:1
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相关领域:理学更多>>
相关期刊:《Chinese Journal of Chemistry》《Chinese Journal of Polymer Science》《有机化学》《CCS Chemistry》更多>>
相关基金:国家自然科学基金更多>>
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A General Electrochemical Synthesis of Sulfonimidoyl Fluorides,Azides,and Acetates
《CCS Chemistry》2024年第8期2021-2030,共10页Yi-Min Jiang Yong-Ying Lin Lingyun Zhu Yi Yu Yuanming Li Yuqi Lin Ke-Yin Ye 
the National Natural Science Foundation of China(grant no.22171046);the Hundred-Talent Project of Fujian(grant no.50021113)is gratefully acknowledged.
Sulfonimidoyl fluorides,the aza-bioisostere of sulfonyl fluorides,are emerging as a promising linkage agent in the sulfur(VI)fluoride exchange reaction(SuFEx).However,conventional synthetic approaches typically requir...
关键词:ELECTROCHEMISTRY click chemistry sulfur(VI)fluoride exchange reaction sulfonimidoyl fluoride SULFINAMIDE 
Enantiomer-selective Living Polymerization of rac-Phenyl Isocyanide Using Chiral Palladium Catalyst被引量:4
《Chinese Journal of Polymer Science》2018年第7期799-804,共6页Jian Huang Ling Shen Hui Zou Na Liu 
financially supported by the National Natural Science Foundation of China (Nos. 51673057, 21622402, and 21574036);N. Liu thanks Anhui Provincial Natural Science Foundation (No. 1608085MB41)
We report the polymerization of phenyl isocyanides with the chiral palladium(II) initiating system. The resulting polymers with optically active properties were obtained by polymerization of the racemic isocyanide m...
关键词:Enantiomer-selective polymerization Kinetic resolution Chiral sulfinamide bisphosphine POLYISOCYANIDES Living polymerization 
Chiral Sulfinamide-Olefin Ligands: Switchable Selectivity in Rhodium-Catalyzed Asymmetric 1,2-Addition of Arylboronic Acids to Aliphatic α-Ketoesters
《Chinese Journal of Chemistry》2013年第3期321-328,共8页Ting-Shun Zhu Ming-Hua Xu 
Financial support from the National Natural Science Foundation of China
Simple and readily available chiral N-(sulfinyl)allylamines have been developed as efficient novel ligands for the rhodium-catalyzed enantioselective 1,2-addition of arylboronic acids to challenging aliphatic a-keto...
关键词:asymmetric catalysis rhodium sulfur-o|efin ligand 1 2-addition stereoselectivity reversal 
Synthesis of Enantionpure tert-Butylsulfinamide from tert-Butylsulfinyloxazolidinone
《有机化学》2004年第z1期250-251,共2页QIN,Yong WANG,Chang-Hui HUANG,Zhi-Yuan XIAO,Xue JIANG,Yao-Zhong 
Project supported by the National Natural Science Foundation of China (No. 20372048) and the Ministry of Education (EYTP).
As a versatile chiral ammonia equivalent, chiral tert-butylsulfinylamide (6) (TBSA) is a very useful auxiliary due to the characteristics of highly stereoselectivity in asymmetric induction and the sulfinyl group bein...
Practical Preparation of tert-Butanesulfinamide Based on Resolution of tert-Butanesulfinate by Molecular Complexation with BINOL
《有机化学》2003年第z1期60-60,共1页SUN Xiao-Xia SUN Shang-Jin LIAO Jian WU Jia-Shou CUI Xin ZHU Jin DENG Jin-Gen 
Since its introduction in 1997, tert-butanesulfinamide (1) has proven to an extremely versatile chiral ammonia equivalent for the asymmetric synthesis of amines[1]. However, practical methods for the preparation of en...
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