染料中含氯苯酚的测定  

Determination of the Content of Chlorinated Phenols in Dye Products

作　　者：季浩[1] 沈日炯[1] 

机构地区：[1]沈阳化工研究院有限公司,沈阳110021

出　　处：《染料与染色》2012年第2期58-61,共4页Dyestuffs and Coloration

摘　　要：本文介绍了染料产品中含氯苯酚的定量测定方法。采用乙酸酐乙酰化衍生的方法处理染料产品中的2,3,5,6-四氯苯酚和五氯苯酚,用DB-5MS毛细管色谱柱进行分离,气相色谱-质谱联用仪进行定性分析,外标法定量。对方法的准确度、精密度进行了测定。本方法对目标化合物的检测限可达到0.1 mg/kg,回收率在90%～100%之间。A quantitative determination method for chlorinated phenols in dye products was introduced.2,3,5,6-Tetrachlorophenol and pentachlorophenol in dye products were acetylated by acetic anhydride,and the derivatives were separated by DB-5MS capillary column,then they were qualified by GC-MS and quantified by external standard method.The accuracy and precision of the method were determined.The detection limit of the test was 0.1 mg/kg for target compounds,average recoveries ranging from 90.0% to 100%.

关 键 词：染料 含氯苯酚 气相色谱-质谱联用 

分 类 号：TQ610.7[化学工程—精细化工] O657.71[理学—分析化学]