Kinetics of Thermal Decomposition for Complex [Zn(C_(16)H_(18)FN_3O_3)_2(NO_3)_2]·2H_2O  

作　　者：张建军 戴玉杰 

出　　处：《Rare Metals》2000年第4期285-289,共5页稀有金属（英文版）

摘　　要：The thermal decomposition reaction of the [Zn(NFA)_2(NO_3)_2]·2H_2O(NFA=C_ 16H_ 18FN_3O_3,norfloxacin) was studied in a static atmosphere using TG-DTG and DTA methods. The thermal decomposition processes of the complex were determined and its kinetics was investigated. The kinetic parameters were obtained from analysis of the TG-DTG curves by differential and integral methods. The most pro- bable mechanism for the second stage was suggested by comparision of the kinetic parameters.The thermal decomposition reaction of the [Zn(NFA)_2(NO_3)_2]·2H_2O(NFA=C_ 16H_ 18FN_3O_3,norfloxacin) was studied in a static atmosphere using TG-DTG and DTA methods. The thermal decomposition processes of the complex were determined and its kinetics was investigated. The kinetic parameters were obtained from analysis of the TG-DTG curves by differential and integral methods. The most pro- bable mechanism for the second stage was suggested by comparision of the kinetic parameters.

关 键 词：Thermal decomposition Non-isothermal kinetics MECHANISMS Zn(Ⅱ) complex NORFLOXACIN 

分 类 号：O643[理学—物理化学]