Prediction of the thermodynamic properties of 1-alkyl-3-methylimidazolium lactate ionic liquids [C_nmim][Lact](n=2,3,4,5,and 6) by parachor  

作　　者：FANG DaWei 1,3,TONG Jing 2,GUAN Wei 2,WANG Han 2 & YANG JiaZhen 1,3 1 Institute of Rare and Scattered Elements Chemistry,Liaoning University,Shenyang 110036,China 2 College of Chemistry,Liaoning University,Shenyang 110036,China 3 Key Laboratory of Rare and Scattered Elements,Liaoning Province,Shenyang 110036,China 

出　　处：《Science China Chemistry》2010年第12期2564-2570,共7页中国科学（化学英文版）

基　　金：supported by the Research Fund of the Education Bureau of Liaoning Province(2009S041,2008S103);the National Natural Science Foundation of China(21003068,20773056,21071073);the Research Fund of Liaoning University

摘　　要：An ionic liquid (IL) based on lactate,1-butyl-3-methylimidazolium lactate ([C4mim][Lact]),has been prepared and characterized by 1H nuclear magnetic resonance (NMR) spectroscopy and differential scanning calorimetry (DSC).Since the IL can form strong hydrogen bonds with water,trace water is a problematic impurity in the IL.Using the standard addition method (SAM),the density,refractive index and surface tension of [C4mim][Lact] were measured in the temperature range (308.15 to 343.15 ± 0.05) K.On the basis of the experimental data,the parachor and molar volume for [C4mim][Lact],and the molecular volume V m,surface tension γ,molar enthalpy of vaporization △lgHm 0,refractive index n D,and the thermal expansion coefficients,for the homologues [Cnmim][Lact] (n=2,3,4,5,and 6) were estimated using semi-empirical methods.The estimated values are in good agreement with the experimental data.An ionic liquid (IL) based on lactate,1-butyl-3-methylimidazolium lactate ([C4mim][Lact]),has been prepared and characterized by 1H nuclear magnetic resonance (NMR) spectroscopy and differential scanning calorimetry (DSC).Since the IL can form strong hydrogen bonds with water,trace water is a problematic impurity in the IL.Using the standard addition method (SAM),the density,refractive index and surface tension of [C4mim][Lact] were measured in the temperature range (308.15 to 343.15 ± 0.05) K.On the basis of the experimental data,the parachor and molar volume for [C4mim][Lact],and the molecular volume V m,surface tension γ,molar enthalpy of vaporization △lgHm 0,refractive index n D,and the thermal expansion coefficients,for the homologues [Cnmim][Lact] (n=2,3,4,5,and 6) were estimated using semi-empirical methods.The estimated values are in good agreement with the experimental data.

关 键 词：parachor LACTATE IONIC liquid DENSITY surface tension refractive index 

分 类 号：O645.1[理学—物理化学]