FT-Infrared and FT-Raman Spectroscopic Studies of Complexes (C_5H_5)_2TiCl_2,(C_5H_4Me)_2TiCl_2 and (C_5HMe_4)_2TiCl_2  

作　　者：JIANG Shi-mei, ZHANG Ping and WANG Yue (Key Laboratory for Supramolecular Structure and Spectroscopy, Department of Material Science, Jilin University, Changchun 130023, P. R. China) 

出　　处：《Chemical Research in Chinese Universities》2000年第4期341-346,共6页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China.

摘　　要：The FT-IR and FT-Raman spectra of complexes (C5H5)2TiCl2(Ⅰ), (C5H4Me)2TiCl2 (Ⅱ) and (C5HMe4)2TiCl2(Ⅲ) have been obtained and discussed. The FT-Raman spectral data pro- vide some new vibrational information about complexes (Ⅰ), (Ⅱ) and (Ⅲ). The assignments of cyclopentadienyl vibrational modes and skeletal vibrational modes have been made.The FT-IR and FT-Raman spectra of complexes (C5H5)2TiCl2(Ⅰ), (C5H4Me)2TiCl2 (Ⅱ) and (C5HMe4)2TiCl2(Ⅲ) have been obtained and discussed. The FT-Raman spectral data pro- vide some new vibrational information about complexes (Ⅰ), (Ⅱ) and (Ⅲ). The assignments of cyclopentadienyl vibrational modes and skeletal vibrational modes have been made.

关 键 词：Spectroscopic study COMPLEX TITANOCENE 

分 类 号：O657.3[理学—分析化学]