云南高校图书馆联盟文献共享服务平台- TITANOCENE

TITANOCENE: 作品数：16被引量：7H指数：2; 导出分析报告; 相关领域：理学更多>>; 相关作者：李云兰宁美英李青山高子伟更多>>; 相关机构：山西医科大学陕西师范大学更多>>; 相关期刊：《Chinese Journal of Structural Chemistry》《Science Bulletin》《色谱》《Science China Chemistry》更多>>; 相关基金：国家自然科学基金教育部“新世纪优秀人才支持计划”中央高校基本科研业务费专项资金陕西省自然科学基金更多>>

Synthesis and Structure of a Titanocene-ferrocenyl Complex: 《Chinese Journal of Structural Chemistry》2009年第3期271-278,共8页王高峰高子伟孙述文高玲香董顺福刘昭铁毋登辉; Supported by the National Natural Science Foundation of China (20771071);the Program for New Century Excellent Talents in University of China,and Natural Science Foundation of Shaanxi Province (2007B06); A titanocene-ferrocenyl complex, （5-ferrocenyl-2-hydroxybenzenecarboxylato- O,O′）-bis（methylcyclopentadienyl）titanium（IV） 4, and an unexpected ionic complex, [C7H8NO3]- [（C5H5）Fe（C5H4）SO3]·H2O3 were synthe...; 关键词：fitanocene FERROCENE HETERONUCLEAR ferrocenesulfonate 4-aminosalicylic acid

正相高效液相色谱法测定有机金属抗癌原料药二氯二茂钛的含量被引量：2: 《色谱》2007年第2期282-283,共2页李云兰宁美英李青山; 国家自然科学基金资助项目(No.30672509);国家教育部新世纪优秀人才支持计划项目(NCET-04-0258);山西省重点科技攻关项目(No.051105-2); 建立了正相高效液相色谱测定有机金属抗癌原料药二氯二茂钛含量的方法。色谱条件为:以Lichrosorb-CN柱(4mm×250mm,5μm)为分离柱,正己烷-二氯甲烷(体积比为50∶50)为流动相,流速为1mL/min,紫外检测波长为254nm,柱温为25℃。以ω-溴代...; 关键词：正相高效液相色谱法(normal—phase high performance liquid chromatography) 二氯二茂钛(titanocene dichloride) 原料药(crude drug)

Hydrogenation of Olefins Catalyzed by Highly Active Titanocene/NaH or n-BuLi Catalyst Systems被引量：1: 《Chemical Research in Chinese Universities》2002年第3期307-310,共4页SUN Qi SUN Ren-an; Supported by the Educational Com mittee of L iaoning Province; The effects of the substituents on the cyclopentadienyl ring and the reducing agents on the catalytic activity and the stability of titanocene/NaH or n BuLi systems for the hydrogenation of olefins were investiga...; 关键词：TITANOCENE Nanometric sodium hydride n Butyllithium Hydrogenation catalyst OLEFIN

FT-Infrared and FT-Raman Spectroscopic Studies of Complexes (C_5H_5)_2TiCl_2,(C_5H_4Me)_2TiCl_2 and (C_5HMe_4)_2TiCl_2: 《Chemical Research in Chinese Universities》2000年第4期341-346,共6页JIANG Shi-mei, ZHANG Ping and WANG Yue (Key Laboratory for Supramolecular Structure and Spectroscopy, Department of Material Science, Jilin University, Changchun 130023, P. R. China); Supported by the National Natural Science Foundation of China.; The FT-IR and FT-Raman spectra of complexes (C5H5)2TiCl2(Ⅰ), (C5H4Me)2TiCl2 (Ⅱ) and (C5HMe4)2TiCl2(Ⅲ) have been obtained and discussed. The FT-Raman spectral data pro- vide some new vibrational information about co...; 关键词：Spectroscopic study COMPLEX TITANOCENE

Reduction of Diaryldiselenides by System of Cp_2TiCl_2/Bu^iMgBr/THF and Its Application in Synthesis of Unsymmetrical Diaryl Selenides: 《Chinese Chemical Letters》2000年第6期473-474,共2页Xin Hua XU Xian HUANG(Institute of Elemento-Organic Chemistry, Nankai University Tianjin 300071Department of Chemistry, Zhejiang University, Xi Xi Campus, Hangzhou 310028); Reduction of diaryldiselenides by the system of Cp2TiCl2/Bu'MgBr/THF gave the nucleophilic arylselenium complex. They reacted with diaryl iodonium salts to afford unsymmetrical diaryl selenides in high yields.; 关键词：Diaryl selenides REDUCTION titanocene dichloride isobutylmagnesium bromide arylselenium complex of titanocene diaryl iodonium salts unsymmetrical diaryl selenides

VISIBLE LIGHT PHOTOPOLYMERIZATION OF METHYL METHACRYLATE COINITIATED WITH TITANOCENE AND KETOCOUMARIN DYE: 《Chinese Journal of Polymer Science》1999年第5期465-470,共6页高放; This work was financially supported by the National Nature Science Foundation of China (Project number: 59773011).; The photosensitive system which can initiate methyl methacrylate with visible light was composed of compound 1 bis( eta-5-cyclopentadienyl)-bis[2,6-difluoro-3-(1-H-pyrrolyl)phenyl]titanium (titanocene) and compound 2 ...; 关键词：photosensitive system PHOTOPOLYMERIZATION photobleaching PHOTOLYSIS electron transfer

Effects of Ligands in Novel Non-titanocene on Syndiotactic Polymerization of Styrene: 《Chemical Research in Chinese Universities》1999年第2期108-111,共4页ZHOU Nai YAN Weidong XIE Guanghua HU Youliang; ＩｎｔｒｏｄｕｃｔｉｏｎＳｙｎｄｉｏｔａｃｔｉｃｐｏｌｙｓｔｙｒｅｎｅ（ｓＰＳ）ｉｓａｈｉｇｈｌｙｃｒｙｓｔａｌｉｎｅｐｏｌｙｍｅｒｗｉｔｈａｍｅｌｔｉｎｇｔｅｍｐｅｒａｔｕｒｅｏｆａｂｏｕｔ２７０℃ａｎｄａｇｌａｓ...; 关键词：Titanium()diketonate Titanium()8hydroxyquinolinate Syndiotactic polystyrene Catalytic performance Syndiotactic polystyrene Catalytic performance

The Chloromethylation Reaction of Substituted Titanocenes(η~5-C_5H_5)(η~5-C_5H_4CRR'C_6H_4X)TiCl_2: 《Chinese Chemical Letters》1998年第5期421-422,共2页Zheng Jie HE You Ming WANG Shou Shan CHEN(Institute of Elemento-Organic Chemistry, Nankai University, Tianin 300071); The chloromethylation reaction of substituted titanocenes (η~5-C_5H_5)(η~5-C_5H_4CRR'C_6H_4X)TiCl2 1 in the presence of polyformaldehyde and dry hydrogen chloride isreported.; 关键词：CHLOROMETHYLATION TITANIUM TITANOCENE REACTIVITY

In vitro antitumor activity of titanocene alanine complex and its interaction with nucleic acids: 《Chinese Journal of Chemistry》1997年第3期225-233,共9页Zhang, ZG Jin, L Yang, P; Titanocene alanine complex, Cp2Ti(O2CCH(CH3)NH3+Cl-)(2), has been found to have in vitro antitumor activity against Ehrlich ascites tumor cells. Study of the interaction between Cp2Ti(O2CCH(CH3)NH3+Cl-)(2) and DNA by ...; 关键词：titanocene alanine complex DNA ANTITUMOR

Ethidium bromide as a fluorescent probe for the interaction mode between titanocene dichloride and DNA被引量：4: 《Chinese Science Bulletin》1996年第13期1098-1103,共6页郭茂林杨频杨斌盛张志刚; Project supported by the National Natural Science Foundation of China;by the Youth Science Foundation of Shanxi Province.; Since the discovery of anticancer efficacy of titanocene dichloride （Cp₂TiCl₂, TDC） by Koepf in 1979, the study of antitumor properties of metallocene complexes is one of the most active subjec...; 关键词：TITANOCENE DICHLORIDE DNA ETHIDIUM BROMIDE FLUORESCENT probe.

TITANOCENE