SYNTHESIS，　STRUCTURE　AND　THERMOREANGEMENT　OF　TRTRA　METHYLDISILANDIYL　BIS（1－INDENYL）　TETRACARBONYL　DI－IRON  

作　　者：Xiu Zhong ZHOU Bai Quan WANG Shan Sheng XU(Department of Chemistry . Nankai University, Tianjin 300071) 

出　　处：《Chinese Chemical Letters》1995年第10期897-898,共2页中国化学快报（英文版）

摘　　要：The title compound (Me2SiSiMe2)[(η5-1-indenyl)Fe(CO)]2(μ-CO)2 was preparedby the reaction of 1 .2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in retluxing heptane inrefluxing xylene can be converted into [Me2Si(η5-1-indenyl ) Fe(CO)2]2.The pure transisomer 2t was obtained and its crystal and molecular structure was determined by X-raydiffraction.The title compound (Me2SiSiMe2)[(η5-1-indenyl)Fe(CO)]2(μ-CO)2 was preparedby the reaction of 1 .2-bis(1-indenyl)tetramethyldisilane and Fe(CO)5 in retluxing heptane inrefluxing xylene can be converted into [Me2Si(η5-1-indenyl ) Fe(CO)2]2.The pure transisomer 2t was obtained and its crystal and molecular structure was determined by X-raydiffraction.

关 键 词：DI METHYLDISILANDIYL TRTRA OF INDENYL BIS AND 

分 类 号：O655.4[理学—分析化学]