INDENYL

作品数:14被引量:6H指数:2
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相关领域:理学更多>>
相关作者:马海燕张雷更多>>
相关机构:华东理工大学更多>>
相关期刊:《Journal of Rare Earths》《Chemical Research in Chinese Universities》《Chinese Journal of Polymer Science》《Chinese Journal of Structural Chemistry》更多>>
相关基金:国家自然科学基金中央高校基本科研业务费专项资金国家教育部博士点基金更多>>
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Ethylene-bridged Indenyl-fluorenyl Metallocene Complexes for Efficient Preparation of Allyl-terminated Propylene Oligomers and Polymers via Selective β-Methyl Transfer被引量:3
《Chinese Journal of Polymer Science》2019年第6期578-590,共13页Lei Zhang Bin Zhang Haiyan Ma 
financially supported by the National Natural Science Foundation of China (No. 21274041);the Key Project of Chinese Ministry of Education (No. 109064);the Fundamental Research Funds for the Central Universities (No. WK1214048)
Four C_1-symmetric ansa-metallocene complexes, C_2H_4(Ind)(2,7-~tBu_2-Flu)ZrCl_2(4), C_2H_4(3-Bn-Ind)(2,7-~tBu_2-Flu)ZrCl_2(5),C_2H_4(3-Bn-Ind)(3,6-~tBu_2-Flu)ZrCl_2(6), and C_2H_4(3-Bn-Ind)(2,7-~tBu_2-Flu)HfCl_2(7), ...
关键词:Metallocene Ethylene-bridged indenyl-fluorenyl ligand PROPYLENE Oligo-/polymerization β-Methyl transfer 
A New Route to Z-5-Fluoro-2-methyl-1- (p-methylsulfinylbenzylidene)-3-indenylacetic Acid and Its X-ray Diffraction Analysis
《Chinese Journal of Chemistry》2006年第10期1443-1446,共4页曾卓 陈超森 金桂芳 赵经纬 朱士正 
Project supported by the National Natural Science Foundation 0f China (No. 20472106).
The title compound (Sulindac) was prepared from the corresponding sulfinyl compound p-methylsulfinylbenzyl bromide by four-step reaction. The sole product (Z)-5-fuoror-2-methyl-l-(p-methylsulfinylbenzylidene)-3-...
关键词:p-methylsulfinylbenzyl bromide Z configuration X-ray crystal structure intermolecular hydrogen bonding 
Indenylnickel(Ⅱ) Halides for the Polymerization of Styrene in the Presence of NaBPh4/PPh3
《Chinese Journal of Chemistry》2006年第3期409-413,共5页孙宏枚 李宛飞 胡冬梅 邵庆 沈琪 
Project supported by the National Natural Science Foundation of China (No. 20272040).
The catalytic activity of a series of indenylnickel(Ⅱ) halides: (1-R-Ind)Ni(PPh3)X (R=ethyl, cyclopentyl and benzyl, while X=Cl, Br and I), towards styrene polymerization was studied in the presence of NaBPh...
关键词:nickel complex INDENYL CATALYST POLYMERIZATION STYRENE 
Synthesis and Crystal Structure of {η~5:η~1-[(2-Methoxyphenyl)-isopropyl]-indenyl}(dimethoxyethylene)lithium1
《Chinese Journal of Structural Chemistry》2005年第9期1046-1048,共3页冯其琴 李一梅 王绍武 周双六 盛恩宏 黄子祥 
This work was supported by the National Natural Science Foundation of China (No. 20472001), the program for NCET (NCET-04-590), and the Excellent Young Scholars foundation of Anhui Province (04046079) and a grant from Anhui Education Department (2005hbz06)
The title compound {η^5:η^1-[(2-MeOC6H4)C3H6]CgH6}Li(DME) (DME=1,2-dimethoxy-ethylene) was synthesized by the treatment of 3-[(2-methoxyphenyl)-isopropyl]-indene with 1 equiv, of n-BuLi followed by the recr...
关键词:INDENYL crystal structure COORDINATION LITHIUM 
Copolymerization of Ethylene/1-hexene and Polymerization of Propylene with Cp-indenyl Zirconium Complexes
《Chinese Journal of Chemistry》2005年第8期1081-1084,共4页张勇 杨晓霞 余亦华 钱延龙 黄吉玲 
Project supported by the Major State Basic Research Development Program(No.G1999064801) the National Natural Science Foundation of China (No. 20372022) and the Research Fund for the Doctoral Program of Higher Education (No. 20020251002).
Complexes (R^1Cp)(R^2Ind)ZrCl2, the catalysts previously reported active for ethylene polymerization showed high activity in ethylene/1-hexene copolymerization and propylene polymerization in the presence of MAO. ...
关键词:INDENYL CYCLOPENTADIENYL zirconium ETHYLENE 1-HEXENE PROPYLENE metallocene complex 
Synthesis of Substituted Indenyl Lanthanide Chloride and Molecular Structure of [(C_5H_9C_9H_6)_2Yb(μ-Cl)_2Li(Et_2O)_2]
《Chinese Journal of Chemistry》2003年第2期153-156,共4页崔冬梅 唐涛 程建华 陈文启 黄葆同 
ProjectsupportedbytheMajorStateBasicResearchDevelopmentProgram (No .G19990 64 80 1) .
Reaction of anhydrous ytterbium trichlorides with 2 equiv. of cyclopentylindenyl lithium in THF solution, followed by removal of the solvent and crystallization of the product from diethyl ether, affords a crystal com...
关键词:INDENYL structure synthesis lanthanide complex 
Polymerization of Acrylonitrile with(Diisopropylamido) Bis(indenyl) Lanthanides
《Journal of Rare Earths》2002年第5期538-540,共3页李刚 张学全 应来强 巴小微 崔冬梅 唐涛 张学全 金鹰泰 
ProjectsupportedbytheKeyLaboratoryofPolymerPhysicsandChemistryinChineseAcademyofSciencesandtheJointFoundationofPolymerChemistryLaboratoryofChineseAcademyofSciencesandChinaPetro ChemicalCorporation
The polymerization of acrylonitrile was studied using (diisopropylamido)bis(indenyl) lanthanides, Ind 2LnN(i Pr) 2(Ln=Y, Yb) as a single component catalyst. The effects of the amount of catalyst, monomer concentr...
关键词:rare earths lanthanide amides ACRYLONITRILE POLYMERIZATION 
Crystal Structure of Indenyl-3-indenyl
《Chinese Journal of Structural Chemistry》2002年第4期389-391,共3页罗梅 马怀柱 苏庆德 
The crystal structure of the title compound (C18H16, Mr = 232.31) has been determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/n with a = 6.3449(9), b = 6.6297(9), c = 15.727(...
关键词:crystal structure DIMER INDENE 
Propylene Polymerization Catalyzed by Bis(R_3-indenyl) Zirconium Bichloride/Aluminoxane──Synthesis of Metallocenes and Influence ofSolvent Polarity on Polymerization
《Chemical Research in Chinese Universities》2001年第4期445-451,共7页YASIN Tariq FAN Zhi-qiang ZHU Yin-bang FENG Lin-xian 
National Natural Science Foundation of China and SINOPEC(No.29734144).
Three unbridged metallocenes, bis(2,4,7-Me3-indenyl)zirconium dichloride(1) , bis(2-Me-4, 7-Et2-indenyl)zirconium dichloride (2) and bis (2, 4, 6-Me3-indenyl) zirconium dichloride (3) were synthesized. The effect of s...
关键词:Propylene polymerization Metallocene catalyst Solvent effect Polarity 
Some Rare Earth Metallic Organohydrides with Biindenyl as the Ligand被引量:3
《Chemical Research in Chinese Universities》2001年第3期338-340,共3页GE Yue YUE Zheng-yu GAO Jin-sheng YAN Peng-fei 
Introduction It is well known that organometallic hydrides of rare earth metals are the catalysts and reducing reagents for the catalysis polymerization of alkenes and the catalysis hydrogenation of alkenoalkynes. The...
关键词:Rare earth metallic hydride Indenyl sodium SYNTHESIS Thermogravimetric analysis 
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