the assistance of the project supported by the National Natural Science Foundation of China(22375157,22401227);the Programme of Introducing Talents of Discipline to Universities(B23025);State Key Laboratory of Electrical Insulation and Power Equipment(EIPE23402,EIPE23405);the China Postdoctoral Science Foundation(2023M742783,GZB20240599);"Medical-Engineering Cross Project of the First Affiliated Hospital of XJTU(QYJCo2)";Shaanxi Postdoctoral Science Foundation(2023BSHYDZZ12)and the"Scientists+Engineers"Team Building Project of Qin Chuang Yuan(2022KXJ-088).
Two families of cyclopentadienyl(Cp)/carboranyl heteroleptic sandwiched organolanthanide complexes,namely[Ln{η^(5):σ-Me_(2)C(C_(5)H_(4))(C_(2)B_(10)H_(10))}_(2)][Li(DME)_(3)](1Ln,Ln=Tb,Dy,Ho,Er)and[2-THF-2'-(μ^(2)-...
financially supported by the National Natural Science Foundation of China (No.21274041)。
A series of C1-symmetric ethylene-bridged ansa-(3-R-cyclopentadienyl)(fluorenyl) metallocene complexes(Zr: 1-5;Hf: 6) have been synthesized, characterized and investigated as catalyst precursors for the high temperatu...
This work was financially supported by the National Natural Science Foundation of China(Nos.22222103,22173015,22025101,21801037,91961114 and 21871039);the Fundamental Research Funds for Central University,China。
The combination of cyclopentadiene,β-diketonate and tripyrazoylborate ligands with dysprosium ion afforded five mononuclear compounds:[(Cp)2Dy(Tp∗)](1Dy),[(Cp)Dy(Tp∗)Cl(THF)](2Dy),[(Cp)Dy(Tp)Cl(THF)](3Dy),[(DBM)Dy(Tp...
supported by the Basic Science Center of Transformation Chemistry of Key Components of Air,National Natural Science Foundation of China(no.21988101).
A series of structurally well-defined iron-dinitrogen complexes(LFe-N2)bearing cyclopentadienylphosphine ligands(L)were synthesized and analyzed by single-crystal X-ray structural analysis,IR/Raman spectra,magnetometr...
financially supported by the National Natural Science Foundation of China (Nos. 51773193 and 21634007);department of science and technology of Jilin province (No.20180101171JC);the "973" project (No. 2015CB654702)
Salt metathesis reactions between pyridyl-methylene-cyclopentadienyl lithium salt and LnCl_3 followed by the addition of two equivalents of LiCH_2SiMe_3 afforded a series of constrained-geometry-configuration rare-ear...
A series of new complexes, CpTiCl[S2P(OR)2]2 (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S2POGO]2 (where G) –CH2CMe2CH2-, -CMe2CMe2-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl ...
The relaxation time of several ferrocene derivatives was measured, and the internal rotation was discussed. For almost all the derivatives, the degree of the internal rotation was constant in spite of the different mo...
A new complexes of Cp2Ti[S2P(OR)2]2 (where R = Et, Pr-n, Pr-i, Bu-i and Ph) and Cp2Ti[S2POGO]2 (where G = -CH2CMe2CH2-, -CH2CEt2CH2- and -CMe2CMe2-) were prepared by the dropwise addition of the appropriate O,O’-dial...
This work was financially supported by the National Natural Science Foundation of China(30830114);the National Basic Research Program of China(973 Program,2009CB522303);The Syngenta postgraduate studentship awarded to Mingming Cao(2012-2015)is appreciated.
Two new daphnicyclidin-type Daphniphyllum alkaloids,daphmacrodins A and B(1 and 2)were isolated from the leaves and stems of Daphniphyllum macropodum.Their structures were elucidated by extensive spectroscopic techniq...
Supported by the National Natural Science Foundation of China (20676012).
Ferrocenium monocations as photoinitiators for cationic photopolymerization suffer from a limitation of low absorption and low reactivity under high-pressure Hg lamp. Here, a ferrocenium dication salt, biphenyl bis [...