financially supported by the National Natural Science Foundation of China (No.21274041)。
A series of C1-symmetric ethylene-bridged ansa-(3-R-cyclopentadienyl)(fluorenyl) metallocene complexes(Zr: 1-5;Hf: 6) have been synthesized, characterized and investigated as catalyst precursors for the high temperatu...
financially supported by the National Iranian Petrochemical Company Research and Technology(NIPC-RT)
Ethylene polymerization was carried out by immobilization of rac-ethylenebis(1-indenyl)zirconium dichloride (Et(Ind)2ZrCl2) and rac-dimethylsilylbis(1-indenyl)zirconium dichloride (Me2Si(Ind)2ZrCl2) preact...
the National Natural Science Foundation of China(No.50573018)
Three ansa-metallocenes(Me_2C)(Me_2Si)Cp_2TiCl_2(1),[(CH_2)_5C](Me_2Si)Cp_2TiCl_2 (2)and (Me_2C)(Me_2Si)Cp_2ZrCl_2 (3)with larger dihedral angles and longer distance from metal to the center of Cp planes were synthesi...