Stereoselective Synthesis of δd-Selanyl Allylic Alcohols by Hydrozirconation of Propargyl Selenides  

作　　者：Mei Hua XIE Xian HUANG 等 

机构地区：[1]DepartmentofChemistry,ZhejiangUniversity,Xi-xiCampus,hangzhou310028 [2]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai

出　　处：《Chinese Chemical Letters》2003年第3期255-256,共2页中国化学快报（英文版）

基　　金：The project was supported by the National Natural Science Foundation of China (No. 29772007).

摘　　要：Hydrozirconation of propargyl selenides afford (E)-3-selanyl vinylzirconocenes chlorides 2. Intermediates 2 reacted with aldehydes to obtain d-selanyl allylic alcohols.Hydrozirconation of propargyl selenides afford (E)-3-selanyl vinylzirconocenes chlorides 2. Intermediates 2 reacted with aldehydes to obtain d-selanyl allylic alcohols.

关 键 词：HYDROZIRCONATION propargyl selenides ALDEHYDES allylic alcohols. 

分 类 号：O623.412[理学—有机化学]