HYDROZIRCONATION

作品数：7被引量：1H指数：1
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相关期刊：《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
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A Novel Stereoselective Synthesis of （1Z,3E）-2-Phenyl（or p-Tolyl）sulfonyl-substituted 1,3-Dienes via Palladium Catalyzed Cross-coupling Reactions of （E）-α-lodovinyl Sulfones
《Chinese Journal of Chemistry》2007年第12期1927-1931,共5页胡荣华 陈桂琴 蔡明中 
Project supported by the National Natural Science Foundation of China （No. 20462002） and the Natural Science Foundation of Jiangxi Province in China （No. 0420015）.
（E）-α-Stannylvinyl phenyl（or p-tolyl）sulfones underwent an iododestannylation reaction to afford （E）-α-iodovinyl phenyl（or p-tolyl）sulfones 1, which reacted with （E）-alkenylzirconium（IV） complexes 2 prod...
关键词：（E）-α-iodovinyl sulfone HYDROZIRCONATION 1 3-dien-2-yl sulfone palladium CROSS-COUPLING 
Stereoselective Synthesis of (E)-α-Aryltellurenylvinyl- stannanes and Their Application in the Synthesis of Stereodefined Trisubstituted Alkenes
《Chinese Journal of Chemistry》2004年第8期859-862,共4页蔡明中 黄佳娣 章荣立 
Project supported by the National Natural Science Foundation of China (No. 20062002).
E)-α-Aryltellurenylvinylstannanes have been synthesized stereoselectively via the hydrozirconation of alkynyl- stannanes, followed by the reactions with aryltellurenyl iodides. (E)-α-Aryltellurenylvinylstannanes ca...
关键词：HYDROZIRCONATION alkynylstannane (E)-α-aryltellurenylvinylstannane trisubstituted alkene stereo-  selective synthesis 
The Preparation of α-Phosphonovinylzirconocenes and their Application in the Stereospecific Synthesis of α-Halo-1 -alkenylphosphonates
《Chinese Chemical Letters》2004年第4期386-388,共3页ZhengChangXIONG LuLingWU XianHUANG 
Hydrozirconation of 1-alkylnylphosphonates gives the organozirconium(Ⅳ) complexes 2 in syn-addition way. Complexs 2 was trapped with NCS, NBS or I2 to afford stereodifined α-halo-1-alkenylphosphonates in moderate to...
关键词：1-Alkynylphosphonates HYDROZIRCONATION a-halo-1-alkenylphosphonates. 
Stereoselective Synthesis of (Z)-α-Bromovinylstannanes and (E)-α-Iodovinylstannanes via Hydrozirconation of Alkynylstannanes
《Chinese Chemical Letters》2004年第3期257-260,共4页MingZhongCAI HongDeYE HongZHAO CaiShengSONG 
Alkynylstannanes 1 react with Cp2Zr(H)Cl (Cp=?-C5H5) giving (Z)--stannylvinyl- zirconium complexes 2, which are trapped with NBS or iodine in THF at 0C to stereoselectively afford (Z)-a-bromovinylstannanes and (E)- a-...
关键词：HYDROZIRCONATION alkynylstannane (Z)--bromovinylstannane (E)- a-iodovinyl- stannane stereoselective synthesis. 
Stereoselective Synthesis of δd-Selanyl Allylic Alcohols by Hydrozirconation of Propargyl Selenides被引量：1
《Chinese Chemical Letters》2003年第3期255-256,共2页Mei Hua XIE Xian HUANG 等 
The project was supported by the National Natural Science Foundation of China (No. 29772007).
Hydrozirconation of propargyl selenides afford (E)-3-selanyl vinylzirconocenes chlorides 2. Intermediates 2 reacted with aldehydes to obtain d-selanyl allylic alcohols.
关键词：HYDROZIRCONATION propargyl selenides ALDEHYDES allylic alcohols. 
A Stereoselective Approach to S-Vinyl Thioesters from Alkynes,Elemental Sulfur and Acyl Chlorides
《Chinese Chemical Letters》2000年第1期1-2,共2页Jun Hua WANG Qing Xu Xian HUANG Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou 310028 
A facile, stereoselective synthesis of S-vinyl thioesters from easily available starting compounds and reagents is showed.
关键词：S-vinyl thioesters HYDROZIRCONATION 
A Novel Stereoseletive Approach to (E)-Vinylic Selenides
《Chinese Chemical Letters》1999年第6期437-440,共4页Jun Hua WANG Xian HUANG(Department of Chemistry. Zhejiang University(Campus Xixi). Hangzhou 310028) 
The insertion of elemental selenium into the Csp(2)-Zr bond of alkenylchloro-zirconocenes affords (E)-vinylseleno zirconocenes, which were trapped by alkyl halides giving (E)-vinylic selenides in moderate to good yields.
关键词：hydrozirconation reaction INSERTION vinylseleno zirconocenes vinylic selenides 
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