A New Lariciresinol-Type Butyrolactone Lignan Derived from Hydroxymatairesinol and Its Identification in Spruce Wood  

出　　处：《天然产物研究与开发》2004年第4期311-311,共1页Natural Product Research and Development

摘　　要：When the natural lignan hydroxymatairesinol ( 1 ) was treated with an alkaline aqueous solution, it partially rearranged to isomeric forms of a lariciresinol-type butyrolactone lignan. The two major diastereomers formed (2 and 3) were isolated by column and medium-pressure chromatography, and their structures were elucidated by MS and NMR techniques. These previously unknown butyrolactone lignans were identified as naturally occurring in spruce knotwood by GC, GC-MS, and HPLC-ESI MS/MS analyses. The formation of isohydroxymatairesinol (2) and epi-isohydroxymatairesinol (3) from hydroxymatalresinol ( 1 ), and their detection in rat urine after administration of 1, is discussed.

关 键 词：落叶松脂素 丁内酯 木聚糖 云杉 鉴定 

分 类 号：Q946.3[生物学—植物学]