定量共振论的应用  

Appling of Quantitative Resonance Theory

作　　者：张爱清[1] 沈长虹[1] 

机构地区：[1]中南民族大学化学与生命科学学院,武汉430074

出　　处：《中南民族大学学报（自然科学版）》2004年第3期27-31,共5页Journal of South-Central University for Nationalities：Natural Science Edition

摘　　要：用共振论解释了一些用其他理论难以解释的问题——振动光谱 (以苯的衍生物为例 )、立体结构 (以苯胺氮原子的杂化为例 )、键长 (以苯的衍生物为例 )以及没有共轭现象的共振作用 (以质子化醛酮为例 ) .A few problems, which are difficult to explain by other theories, are explained by quantitative resonance theoryvibration spectrum (with the example of benzene derivatives),stereotructure (the hybridation of nitrogen atom of aniline),bond length (benzene derivatives),and resonance without conjugation (with the example of protonized carbonyl compounds).

关 键 词：共振论 权值 化学位移 振动光谱 键长 苯胺 

分 类 号：O621.13[理学—有机化学]