中性铜(Ⅰ)卤结构单元及其配位聚合物化学  

Structural Units and Coordination Polymer Chemistry of Neutral Copper(Ⅰ) Halide Cluster

作　　者：于杰辉[1] 别海英[1] 徐吉庆[1] 王铁钢[1] 

机构地区：[1]吉林大学化学学院无机合成与制备化学国家重点实验室,长春130023

出　　处：《无机化学学报》2004年第11期1249-1256,共8页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.20271021和20333070)

摘　　要：铜髣卤簇合物的结构化学极其丰富多彩。一方面,以单齿或是多齿螯合型有机配体为辅助配体,铜髣卤自身可形成多种结构类型的孤立的簇或是低聚物,0维的如菱形的二聚体、立方烷型的或是椅式的四聚体,一维的如锯齿链或是楼梯链等等。若有机配体具有桥联性质,将桥联孤立的簇或是低聚物形成高维聚合物。本文以文献工作为主,结合自身工作,介绍有关中性铜髣卤簇化合物在结构方面的发展概况。Copper halide clusters show a variety of frameworks in the structure chemistry. On one hand, with the monodentate or bidentate chelate organic ligands as the ancillary ones, copper(Ⅰ) halides can form oligomeric (normally dimers or tetramers) and polymeric (zigzag or staircase chains) frameworks themselves. On the other hand, once the ligands possess bridging nature, these discrete clusters, 1-dimensional or 2-dimensional polymers will be further propagated into high-dimensional sheets or networks. Based on the literature and our group's works, this article introduces mainly the evolutive survey of copper(Ⅰ) halide clusters in the structure chemistry.

关 键 词：铜卤化合物 中性化合物 配位聚合物 有机分子协同 有机分子桥联 

分 类 号：O614.121[理学—无机化学] O641.4[理学—化学]