supported by the National Natural Science Foundation of China(21173100 and 21320102001)~~
The catalytic epoxidation of olefin was investigated on two copper complex-modified molybdenum oxides with a 3D supramolecular structure, [Cu(bipy)]4[Mo15O47].2H2O (1) and [Cu1(bix)][(Cu1bix) (δ-MoVl8O26)0....
The title compound [N(CH 3) 4] 4 [H 5PMo 5V 9O 42 ] ·3.5H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X ray analysis. The cluster anion is a bicapped Keggin polyanio...