绝热式热动力学的研究 Ⅳ.可逆反应的热谱解析  

Studies on Adiabatic Thermokinetics Ⅳ. Thermokinetic Research of Reversible Reactions

作　　者：詹曙光[1] 刘劲松[1] 曾宪诚[1] 邓郁[1] 安慕辉[2] 

机构地区：[1]四川大学化学系,成都610064 [2]中国科学院成都有机化学研究所,成都610015

出　　处：《化学学报》1993年第10期937-942,共6页Acta Chimica Sinica

基　　金：国家自然科学基金

摘　　要：本文建立了可逆反应在绝热系统中的热动力学研究法,并用自制的绝热式自动热量计,研究了三个可逆反应体系的热动力学,验证了本文方法的正确性。An adiabatic thermokinetic research method of the reversible reactions is proposed and has been used to study three reversible reaction systems in this paper. Both rate constants and equilibrium constants of these reactions calculated are in agreement with the values in literatures. And therefore, the validity of this method and its theoretical basis should be proved.

关 键 词：绝热式热量计 可逆反应 量热法 

分 类 号：O643.13[理学—物理化学]