Hydroaminomethylation of 1-Dodecene Catalyzed by Water-soluble Rhodium Complex  

作　　者：YingYongWANG MeiMingLUO YaoZhongLI HuaCHEN XianJunLI 

机构地区：[1]DepartmentofChemistrySichuanUniversity,Chengdu610064 [2]InstituteofHomogeneousCatalysisSichuanUniversity,Chengdu610064

出　　处：《Chinese Chemical Letters》2004年第7期774-776,共3页中国化学快报（英文版）

摘　　要：The hydroaminomethylation of 1-dodecene catalyzed by water soluble rhodium complex RhCl(CO)(TPPTS)2 in the presence of surfactant CTAB was investigated. High reactivity and selectivity for tertiary amine were achieved under relatively mild conditions.The hydroaminomethylation of 1-dodecene catalyzed by water soluble rhodium complex RhCl(CO)(TPPTS)2 in the presence of surfactant CTAB was investigated. High reactivity and selectivity for tertiary amine were achieved under relatively mild conditions.

关 键 词：HYDROAMINOMETHYLATION 1-DODECENE water-soluble rhodium complex biphasic catalytic system. 

分 类 号：O623.123[理学—有机化学]