稀土化合物Yb(OTf)_3催化的有机合成反应的最新进展  

Advance in Yb(OTf)_3 Catalyzed Organic Synthesis Reactions

作　　者：王利民[1] 盛佳[1] 田禾[1] 

机构地区：[1]华东理工大学精细化工研究所华东理工大学结构可控先进功能材料教育部重点实验室,上海200237

出　　处：《中国稀土学报》2004年第6期725-733,共9页Journal of the Chinese Society of Rare Earths

基　　金：华东理工大学校科研基金;华东理工大学结构可控先进功能材料教育部重点实验室科研基金

摘　　要：研究和开发环境友好的有机合成反应是"绿色化学"研究的一个重要内容,其中也包括新型绿色催化剂的研究。本文对近两年来Yb(OTf)3作为催化剂的有机合成反应按照反应类型进行了综述。进一步总结和拓展了Yb(OTf)3的催化范围,证明了稀土化合物广泛的应用前景。Rare earth compounds have played more and more important roles in the course of carrying out the concept of 'green chemistry' which concerning the researching of environmental friendly organic reactions and 'green' catalysts because of their fantastic properties such as the water tolerability and easy recyclability. The very recent works in this field according to the type of reactions were reviewed. The application of (Yb(OTf)_3) as an efficient catalyst was further concluded was further concluded and developed.

关 键 词：催化化学 绿色化学 LEWIS酸 Yb(OTf)3 稀土 

分 类 号：O643.3[理学—物理化学]