W离子注入Ni—Mo合金电极的析氢性能  被引量:5

Hydrogen Evolution Behavior of W-Ion Implanted Ni-Mo Surface Alloys Electrodes

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作  者:张季爽[1] 李青莲[1] 吕瑶姣[1] 言喜云 

机构地区:[1]湖南大学化学化工系,长沙410082

出  处:《化学学报》1994年第5期489-491,共3页Acta Chimica Sinica

基  金:国家自然科学基金资助的课题

摘  要:本文在镍基上电沉积Ni-Mo合金层,用W^+束注入,得到活性和稳定性极佳的新型析氢电极.The electrodes containing Ni, W, Mo were obtained by implanten W into Ni-Mo surface alloys. The alloys was prepared by electrodepositing on Ni substrate. The hydrogen overvoltage decreasing comparing with mild steel is 235mV (48℃) in 0.5mol / dm H2SO4solu-tion and 295mV (38℃) in 1mol/ dm3NaOH solution. The cathodes showed stable potentials during water electrolysis by 300mA/ cm2 in acid medium more than 16 days. The strike-resistant stability of the cathodes was higher than others ones.

关 键 词:离子注入  析氢电极 镍钼合金 

分 类 号:O646.54[理学—物理化学]

 

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