水相金属有机化学  

Aqueous Organometallic Chemistry

作　　者：邓道利[1] 陆忠辉[1] 吴可 

机构地区：[1]中国科学院上海有机化学研究所,上海200032

出　　处：《有机化学》1994年第4期337-349,共13页Chinese Journal of Organic Chemistry

摘　　要：本文对近年来锡、锌、铋等介入下的水相金属有机化学作了综述。特别对水相Barbier反应作了较详细的介绍,同时也描述了一些典型的水相金属有机反应,如Immonium阳离子的烷基化反应,α,β不饱和化合物的共轭加成,醇醛缩合反应及水溶性金属有机化合物的反应等。某些反应的机理也被讨论。In this paper the recent developments in the new field of the organometallic chemistry in aqueous media using tin, zinc or bismuth are reviewed. The Barbier-type reactions in aqueous media have been discussed in more detail. Also other typical reactions in aqueous media, such as alkylations of immonium cations, conjugate additions to α,β, unsaturated carbonyl compounds and crossed aldol type condensation. The syntheses and reactions of water-soluble organometallic compounds are also described. The mechanisms of some reactions have been suggested.

关 键 词：BARBIER反应 金属 有机化合物 

分 类 号：O621.391[理学—有机化学]