环境水样中亚硝酸盐和硝酸盐监测方法研究  

Research on Monitoring Method for Nitrite and Nitrate in Environmental Water

作　　者：龚正君[1] 章竹君[2] 

机构地区：[1]西南交通大学环境科学与工程学院,四川成都610031 [2]西南师范大学分析科学研究所,重庆400715

出　　处：《西南交通大学学报》2005年第2期277-280,共4页Journal of Southwest Jiaotong University

基　　金：国家自然科学基金资助项目(20175039)

摘　　要：试验发现,硝酸根在海绵锌-镉还原剂的存在下被还原为亚硝酸根.基于这一试验结果,采用H2O2-鲁米诺化学发光体系对亚硝酸盐和硝酸盐进行在线分析,建立了同时测定亚硝酸盐和硝酸盐的新方法.用此法测定亚硝酸根的线性范围为3×10-3 ～3 mg/L,检出限为1.5×10-3 mg/L;测定硝酸根的线性范围为1～100 mg/L,检出限为0.33 mg/L.此法已用于天然水样中亚硝酸盐和硝酸盐同时监测,结果表明,最大相对标准偏差不超过4%.An experiment shows that nitrate can be reduced to nitrite by spongiform zinc-cadmium reducer. Based on the experimental result, the chemiluminescence of hydrogen dioxide and luminol solution was used to the on-line analysis of nitrite and nitrate. As a result, a new chemiluminescence method for the simultaneous determination of nitrite and nitrate was proposed. The system responds linearly in the range of 3 × 10-3 -3 mg/L for nitrite and 1-100 mg/L for nitrate, and the detection limits for nitrite and nitrate are 1.5 × 10-3 and 0.33 mg/L respectively. This method has been used to determine nitrite and nitrate in environmental water samples. The result shows that the maximum relative standard deviation is less than 4%.

关 键 词：亚硝酸盐 硝酸盐 化学发光 环境监测 流动注射分析 

分 类 号：X131.2[环境科学与工程—环境科学]