稀土异羟肟酸配合物的快原子轰击质谱研究  

Study on FABMS of Solid Coordination Compounds of Rare Earth with Hydroxamic Acid

作　　者：袁谋村 朱育芬[1] 罗运[1] 刘光华[1] 周华 温汉辉 

机构地区：[1]中国科学院广州化学研究所,湘潭大学化学系,江西大学化学系,中华人民共和国广州卫生检疫所,中山大学测试中心

出　　处：《质谱学报》1994年第1期54-59,共6页Journal of Chinese Mass Spectrometry Society

摘　　要：本文报道了两类稀土异羟肟酸配合物的正、负离子快原子轰击质谱（ＦＡＢＭＳ），通过分析ＦＡＢＭＳ特征离子讨论了配合物溶液中的配体交换反应及离解反应。Fast atom bombardment mass spectra (FABMS) of solid corrdination compounds ofrare earth with hydroxamic acid were reported. A certain relationship was found between the intensities of ions in gas phase and their reactions in solution, that was coincident with the direct sputtering mechanism on FABMS. Therefore, FABMS could beconsidered as a useful method to study solution reactions of coordination compound.

关 键 词：稀土配合物 异羟肟酸 质谱 FABMS 

分 类 号：O614.33[理学—无机化学]