四-β-(2-甲基-8-喹啉氧基)酞菁锌(Ⅱ)的合成、表征及其Uv/Vis光谱研究  

Synthesis, characterization and study of Uv/Vis spectra of tetra-β-(2-methyl-8-quinolinoxy) phthalocyanine zinc(Ⅱ)

作　　者：洪湖铭[1] 薛金萍[1] 孙纲春[1] 陈耐生[1] 黄金陵[1] 

机构地区：[1]福州大学化学化工学院,福建福州350002

出　　处：《福州大学学报（自然科学版）》2005年第3期382-386,390,共6页Journal of Fuzhou University(Natural Science Edition)

基　　金：福建省自然科学基金计划资助项目(项目编号:E0310013);福建省科技厅国际合作资助项目(项目编号:2003I018);福州大学科技发展基金资助项目(项目编号:2003-XQ-08);福州大学博士后流动基金资助项目(项目编号:XJBH-0402)

摘　　要：利用4-硝基邻苯二甲腈和2-甲基-8-羟基喹啉在碱环境下,DMF溶液中反应得到4-(2-甲基8-喹啉氧基)邻苯二甲腈,对其进行了元素分析、IR光谱、1HNMR谱、质谱表征.进一步利用DBU催化法合成得到四-β-(2-甲基-8-喹啉氧基)酞菁锌(Ⅱ),并对其进行了元素分析、Uv/Vis、IR、质谱表征.同时对该化合物的Uv/Vis光谱进行研究,探讨其在不同溶剂中的聚集行为.4-(2-methyl-8-quinolinoxy)phthalonitrile was synthesized by stirring 4-nitrophthalonitrile and 2-methyl -8-hydroxyquinoline in DMF in the presence of alkali. It was characterized by (element) analysis, IR, ()~1HNMR and mass spectrum, and was able to condensate to form tetra-β -(2-methyl -8-quinolinoxy) phthalocyanine zinc(Ⅱ) by 'DBU method', which was characterized by (element) analysis, Uv/Vis, IR and MS. The UV/Vis spectrum of tetra-β -(2-methyl -8-quinolinoxy) phthalocyanine zinc(Ⅱ) was studied and it's congregate behavior in different solvents was discussed.

关 键 词：2-甲基-8-喹啉氧基 酞菁锌 合成 表征 光谱 

分 类 号：O611.4[理学—无机化学] O614.8[理学—化学]