新型一维链状化合物N-(m-二茂铁苯基)甲酰胺的合成及晶体结构(英文)  

Synthesis and Crystal Structure of a Novel One-Dimensional N-(m-Ferrocenylphenyl)-Formamide

作　　者：徐琰[1] 付勇[1] 冉春玲[1] 王非[1] 冶保献[1] 宋毛平[1] 

机构地区：[1]郑州大学化学系河南省应用化学重点实验室,郑州450052

出　　处：《无机化学学报》2005年第7期1045-1048,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No20072034);郑州大学青年骨干教师基金资助项目。

摘　　要：N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, 1H NMR, and X-ray structure determination. The crystallized was in the monoclinic, P21/c space group, with a=0.140 94(3) nm, b=0.102 87(2) nm, c=0.100 26(2) nm, β=104.85(3)° and final R indices [I>2σ(I)] R1=0.072 7, wR2=0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding N-H...O. Cyclic voltammetry was studied comparing with the parent compound (m-ferrocenylaniline). CCDC: 243511.N-(m-ferrocenylphenyl)-formamide has been synthesized by the reaction of m-ferrocenyl-aniline with DMF, and characterized by elements analysis, IR, H-1 NMR, and X-ray structure determination. The crystallized was in the monoclinic, P2(1)/c space group, with a=0.140 94(3) nm, b=0.102 87(2) run, c=0.100 26(2) nm, beta=104.85(3)degrees and final R indices [I > 2 sigma,(I)] R-1 = 0.072 7, wR(2) = 0.184 5. An infinite one-dimensional chain is formed by intermolecular hydrogen bonding N-H...O. Cyclic voltammetry was studied comparing with the parent compound (mferrocenylaniline).

关 键 词：链状化合物 晶体结构 甲酰胺 二茂铁 elements analysis BONDING 合成 苯基 一维 with space group FINAL chain the and was DMF ^1H NMR The IR 

分 类 号：O623.423[理学—有机化学] O614.121[理学—化学]