铜胺络合物作用下取代2-萘酚的交叉偶合反应  

Study on Cross-coupling Reactions of Substituted 2-Naphthols Promosted by Copper(II)-amine Complex

作　　者：王秀珍[1] 庞冀燕[1] 汪波[1] 许遵乐[1] 

机构地区：[1]中山大学化学与化学工程学院,广州510275

出　　处：《有机化学》2005年第7期859-861,i005,共4页Chinese Journal of Organic Chemistry

基　　金：广东省自然科学基金(No.011179)资助项目.

摘　　要：在铜(II)-胺络合物作用下,取代2-萘酚化合物进行交叉偶合反应,得到几种结构新颖的取代1,1'-联-2-萘酚化合物,产率44%～90%.化合物的结构经过核磁、红外光谱及质谱进行确证.The cross-coupling reaction of substituted 2-naphthols in the presence of copper(II)-amine complex was described. Several novel asymmetrically substituted bi-naphthol compounds were obtained in yields of 44%～90%. The structures of these compounds were characterized by 1H NMR, IR and FAB-MS spectra.

关 键 词：偶合反应 铜胺络合物 2-萘酚 交叉 酚化合物 红外光谱 结构 质谱 

分 类 号：O621.25[理学—有机化学]