酞菁钴－高分子双层膜修饰电极对氧的催化电还原  

Oxygen Reduction on the Glassy Carbon Electrodes Modified with Two Film of Polymer and Cobaltphthalocyanine

作　　者：董国孝[1] 李纪生[1] 庄瑞舫[1] 

机构地区：[1]中国科学院北京化学研究所,南京大学配位化学研究所

出　　处：《高等学校化学学报》1996年第5期794-796,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金

摘　　要：酞菁钴－高分子双层膜修饰电极对氧的催化电还原董国孝，李纪生，庄瑞舫（中国科学院北京化学研究所，北京，１０００８０）（南京大学配位化学研究所）关键词酞菁合钴，双层膜修饰电极，电还原金属酞菁配合物的催化活性和电催化活性已引起化学家们的极大兴趣，它们作为电...Phthalocyanine-2,9,16, 23-tetracarboxylic acid cobalt complex(1)and phthalocyanine-2,9, 16, 23-tetracarboxyl tetrachloride cobalt complex(2) were synthesized.The glassy carbon electrodes coated with polyethylpyridine film or polyaniline film were made by electrochemical methods. Chemically modified electrodes(CMEs)were prepared by precipitation of 1 from its solution to the electrode coated with the polyethylpyridine film or electrode coated with the polyaniline film, and by precipitation of 2 from its solution to the electrode coated with polyaniline film. Catalytic activities and lifetime of these CMEs were investigated to electroreduction dioxygen in aqueous solution with cyclic voItammogram. ElectrodeⅠcoated with 1 and polyethylpyridine showed activity in 0.2 mol/L potassiumchloride aqueous solution. ElectrodeⅡcoated with 1 and polyaniline was the same active as electrode Ⅲ coated with 2 and polyaniline in 1.0 mol/L hydrogen sulfate aqueous solution which was active during a long continuous operation.Ⅲ had a longer life thanⅠand Ⅱ.

关 键 词：酞菁合钴 双层膜修饰电极 电还原 

分 类 号：O643.36[理学—物理化学] O613.3[理学—化学]