新型单膦配位羧酸银配合物的合成、表征及其热稳定性的研究(英文)  

New Monophosphine Coordinated Silver Carboxylates:Synthesis,Characterization and Thermal Stability

作　　者：韩建林[1] 杨宝海[1] 颜黎均[1] 沈应中[1] 潘毅[1] 

机构地区：[1]南京大学化学化工学院,配位化学国家重点实验室,南京210093

出　　处：《无机化学学报》2005年第11期1710-1714,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家863计划项目;江苏省精细石油化工重点实验室经费资助。

摘　　要：A new series of diphenyl(2-methoxyphenyl)phosphine coordinated silver carboxylates [Ag(O2CR)(L): L=Diphenyl(2-methoxyphenyl)phosphine, R=CH3 (3a), CH3CH2 (3b), i-Pr (3c), EtOCH2 (3d), p-CH3OPh (3e), CH3CH=CH (3f), (CH3)2C=CH (3g), ClCH2 (3h)] were synthesized by reaction of diphenyl(2-methoxyphenyl)phosphine with the related silver carboxylates in chloroform. The complexes were obtained as white solids in high yields and their structures have been characterized by elemental analysis, 1H NMR, 13C NMR, 31P NMR, IR spectroscopy. The thermal stability of these complexes has been studied by the TG analysis. These complexes can be used in the growth of metal thin films via aerosol-assisted chemical vapor deposition (AACVD) techniques.A new series of diphenyl（2-methoxyphenyl）phosphine coordinated silver carboxylates [Ag（O2CR）（L）： L= Diphenyl（2-methoxyphenyl）phosphine, R=CH3（3a）, CH3CH2 （3b）, i-Pr （3c）, EtOCH2 （3d）, p-CH3OPh （3e）, CH3CH= CH （3f）, （CH3）2C=CH（3g）, ClCH2（3h）] were synthesized by reaction of diphenyl（2-methoxyphenyl）phosphine with the related silver carboxylates in chloroform. The complexes were obtained as white solids in high yields and their structures have been characterized by elemental analysis,^1H NMR, ^13C NMR, ^13p NMR, IR spectroscopy. The thermal stability of these complexes has been studied by the TG analysis. These complexes can be used in the growth of metal thin films via aerosol-assisted chemical vapor deposition （AACVD） techniques.

关 键 词：羧酸银配合物 膦 CVD TG 

分 类 号：O614.122[理学—无机化学]