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作 者:蒋剑春[1] 邓先伦[1] 张燕萍[1] 施荫锐[1]
机构地区:[1]中国林业科学研究院林产化学工业研究所,江苏南京210042
出 处:《林产化学与工业》2005年第B10期15-18,共4页Chemistry and Industry of Forest Products
摘 要:主要研究了竹材在快速热解与常规热解下液相、固相及气相产品的得率差异。快速 热解下升温28℃/s,停留时间0.76 s,温度500℃,液相产品竹焦油得率为48.5%,主要组分 为2,6-二甲氧基苯酚和2-甲氧基苯酚(愈疮木酚),在常规热解下升温速率1℃/min,温度 500℃,液相得率为30%(包括水),组分主要为乙酸。在常规或缓慢热解中,固相产物,炭的 微孔结构中。当热解温度低于550℃的情况下,主要孔径在6.0-22.0 nm,当热解温度在650-750℃,主要孔 径<2 nm。The characteristic feature of flash pyrolysis and conventional pyrolysis of bamboo were investigated. The operating conditions of flash pyrolysis was : temperature 500 ℃, residence time of volatile matter 0.76 s and heating rate 28 ℃/s. The yield of the liquid product was 48.5 %, containing 2,6-dimethoxy phenol and 2-methoxy phenol as major constituents. The processing condition of conventional bamboo pyrolysis was: heating rate 1℃/min and temperature 500 ℃. The yield of liquid products including water was 30 %, containing acetic acid as major constituent. In conventinal pyrolysis at temperature less than 550 ℃, the main pore diameters were 6.0 - 22.0 nm. At pyrolysis temperature 650 -750 ℃, the main pore diameters were less than 2 nm.
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