七元瓜环与金刚烷胺及其衍生物的相互作用  

Interacion of Cucurbit[7]uril with Amantadine and its derivates

作　　者：刘静欣[1] 陶朱[1] 薛赛凤[1] 祝黔江[1] 张建新 

机构地区：[1]贵州大学应用化学研究所,贵州贵阳550025 [2]贵州省天然产物重点实验室,贵州贵阳550002

出　　处：《贵州大学学报（自然科学版）》2005年第4期392-397,共6页Journal of Guizhou University:Natural Sciences

摘　　要：作为一种比较新颖的大环化合物,七元瓜环是一个很好的分子容器。实验表明它可包容如金刚烷胺及其衍生物,这一结论得到了1H NMR及2D NMR技术、质朴等方法的证实。Cucurbit[7]uril, one kind of a relatively new family of molecular hosts, is a new molecular container shell. Evidence for molecular container assembly of Amantadine hydrochloride, and its derivates within cucurbit[ 7 ] uril is elaborated. Induced chemical shifts of guests encapsulated into cucurbit[ 7 ] uril are noted. The structures of the self-assembling molecular complex are characterized by ^1H NMR and MS spectra.

关 键 词：七元瓜环 NMR技术 质谱 

分 类 号：O621.3[理学—有机化学]