二乙酰基二茂铁二腙的合成  

The Synthetic of Two Acetyl and Two Luxuriant Irons and Two Arbazone

作　　者：张新友[1] 韩雪松[2] 廖世国 

机构地区：[1]白城师范学院化学系,吉林白城137000 [2]中国科学院长春光学精密机械与物理研究所医院,吉林长春130033 [3]吉林省延边二中,吉林延吉133000

出　　处：《吉林师范大学学报（自然科学版）》2005年第4期38-39,共2页Journal of Jilin Normal University:Natural Science Edition

摘　　要：用三氯甲烷作溶剂、三氯化铝作催化剂的条件下进行Friedel-Crafts酰基化反应,合成了1,1’-二乙 酰基二茂铁,其产率为55％．1,1’-二乙酰基二茂铁,在少量盐酸催化下用无水乙醇作溶剂,合成了二乙酰基二 茂铁二腙．Make solvents with the chloroform, Three chlorine aluminium reglect friedel - Crafts aeyl base under the terms to make catalyst. Formate 1,1＇- two acetyl 2 luxuriant iron, Its producing rate is 55%. 1,1 ＇ - two acetyl two luxuriant iron, hydrazine make solvents with the anhydrous ethanlol under the hydroger catalysis in a small amount of chlorine , formate one two luxuriant two acetyl and two luxuriant iron and two ambazone of complexing material of iron.

关 键 词：二乙酰基二茂铁 肼 schiff应 二乙酰基二茂铁二腙 

分 类 号：O621.3[理学—有机化学]