气液色谱法研究双—（o，o′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质  

Study on the Electrolytic Formation of AgO on the Silver Electrode in KOH Solution with In-Situ X-ray Diffration

作　　者：沈小平[1,2] 项明长 朱多林[1,2] 俞运鹏 

机构地区：[1]镇江师范专科学校化学系 [2]镇江市教育委员会

出　　处：《南京师大学报（自然科学版）》1996年第3期46-48,共3页Journal of Nanjing Normal University(Natural Science Edition)

基　　金：江苏省教育委员会自然科学基金

摘　　要：用气液色谱法研究了双—（ｏ，ｏ′—二正辛基二硫代磷酸酯）合镍（Ⅱ）与环戊酮加合反应的热力学性质，测定了３３３．２～３６３．２Ｋ范围内加合反应的平衡常数，用最小二乘法求得反应的ΔＨ和ΔＳ．Cyclic voltammetry has been used to study the electrolytic formation of AgO at a silver electrode in aqeous KOH solutions.A range of concentrations of KOH and sweep rates have been used.The conditions under which an anodic peak appears on the negative-going sweep have been determined. The products AgO which formed at the reversed peak are in situ characterized with X-ray diffraction.

关 键 词：气液色谱法 磷酸酯 环戊酮 镍配合物 酸碱反应 

分 类 号：O621.25[理学—有机化学] O624.421[理学—化学]