簇合物[（η^5-C5Me5）WS3{Cu（PPh3））3Cl]（PF6）的合成及晶体结构  

Synthesis and Crystal Structure of an Organometallic Tetranuclear Cationic Cluster [（η^5-C5Me5）WS3{Cu（PPh3））3Cl]（PF6）

作　　者：虞虹[1] 张文华[1] 曹向前[1] 陈阳[1] 任志刚[1] 郎建平[1] 

机构地区：[1]江苏省有机合成重点实验室,苏州大学化学化工学院,苏州215123

出　　处：《无机化学学报》2006年第1期187-190,共4页Chinese Journal of Inorganic Chemistry

基　　金：江苏省自然科学研究基金资助项目(No.BK2004205);江苏省有机合成重点实验室开放基金资助项目(No.JSK001);苏州大学青年教师研究基金项目(No.Q3109510)。

摘　　要：Reaction of a preformed cluster [｛(η5-C5Me5)WS3｝3Cu7(MeCN)9](PF6)4 (1) in MeCN with LiCl and PPh3 gave rise to a tetranuclear cationic cluster [(η5-C5Me5)WS3｛Cu(PPh3)｝3Cl](PF6) (2). The title compound 2 was char- acterized by elementary analysis, IR, UV-Vis, 1H NMR, and its crystal structure was determined by X-ray single crystal diffraction. It belongs to monoclinic, space group P21/c with a=1.7998(4) nm, b=2.0836(4) nm, c=1.9135(4) nm, β=113.63(3)°, V=6.574(3) nm3, Z=4. The cluster cation [(η5-C5Me5)WS3｛Cu(PPh3)｝3Cl]+ of 2 contains a strongly distorted, cubane-like structure [WS3Cu3Cl] in which one Cl weakly fills into the void of the nido-like [WS3Cu3] fragment with three relatively long Cu-Cl distances. CCDC: 270415.Reaction of a preformed cluster [（η^5-C5Me5）WS3{Cu（PPh3））3Cl]（PF6）4 （1） in MeCN with LiCl and PPh3 gave rise to a tetranuclear cationic cluster [（η^5-C5Me5）WS3{Cu（PPh3））3Cl]（PF6）（2）. The title compound 2 was characterized by elementary analysis, IR, UV-Vis, ^1H NMR, and its crystal structure was determined by X-ray single crystal diffraction. It belongs to monoclinic, space group P21/c with a=1.799 8（4） nm, b=2.083 6（4） nm, c=1.913 5（4） nm, β3=113.63（3）°, V=6.574（3） nm^3, Z=4. The cluster cation [（η^5-C5Me5）WS3{Cu（PPh3））3Cl]^＋ of 2 contains a strongly distorted, cubane-like structure [WS3Cu3Cl] in which one Cl weakly fills into the void of the nido-like [WS3Cu3] fragment with three relatively long Cu-Cl distances. CCDC： 270415.

关 键 词：钨簇合物 铜簇合物 晶体结构 合成 

分 类 号：O614.613[理学—无机化学] O614.121[理学—化学]